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Water Quality Monitoring Report - Noosa Civic - November 2009-2010 - Eenie Creek Rd NOOSAVILLE · 132002.220285
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u 11 B0360121
STOCKWEII
STOCKWELL PROPERTY
MANAGEMENT Pn LM
Centre Management
28 Eenie Creek Road
PO Box 2075
Noosaville BC QLD 4566
_ 9q? T 07 5440 7900
F 07 5440 7999
Box: (
(^?
:1 www.noosacivic.com.au
www.stockwell. com.au
ABN 16 071 893 402
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Page 2
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Our Reference: AF0923L
Friday, 8 April 2011
Stockwell (Noosa Civic)
PO Box 2075
Noosaville Qld 4566
Attention: Steve Massey
Dear Steve
WATER QUALITY MONITORING REPORT FOR 2009/2010
ow
NOOSA CIVIC
28 EENIE CREEK ROAD, NOOSAVILLE QLD 4566
Please find enclosed three (3) copies of the Water Quality Monitoring Report for
November 2009 - November 2010 for the above mentioned project.
We have provided sufficient copies so that you may forward a copy to head office
and a copy to Council.
If you have any questions, please do not hesitate to contact Ms Julie Schubert of
this office.
Yours sincerely
J.
- ,.o
ulie Schubert - 00
Projects Coordinator
For Duke Environmental
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Enc. Report AE0923WQM
AF0923L - Stockwell Property Management Pty Ltd
April 2011
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STEVE MASSEY STOCKWELL
07 5440 7900
28 Eenie Creek Road 07 5440 7913
Noosaville QLD 4566 0448 104 433
PO Box 2075 07 5440 7999
Noosaville BC QLD 4566 [email protected]
www.noosacivic.com.au
www.stockwell.com.au
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Suite 7, Level 1
15 Nicklin Way PO Box 78
Duke
MINYAMA QLD 4575
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WURTULLA QLD 4575
07 5493 3322 F 07 5493 3422 E deuu,dukenviro.com.au Environmental
Environmental Management Consultants
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07 5493 3322
07 5493 3422
[email protected] Duke
PO Box 78 Wurtulla 4575
Powerful Owl Qld Ply Ltd
T/A Duke Environmental
Environmental
ABN 53 111 368 944 Environmental Management Consultants
Document Control
Version Parenthood Authorised for Issue
No. Date Author Reviewer Name Document Status
0 31/03/11 Stephen Hayes Paula Duke Julie Schubert A
A -Approval B - Building Approval C- Construction V - Version
T - For Tender X - Information P -Preliminary
The content of this document is provided in strict commercial confidence. The content
of this document shall not be disclosed to any third party, without the express written
authority of Duke Environmental. Copyright © Duke Environmental 2011.
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TABLE OF CONTENTS
1.0 INTRODUCTION ...................................................................................................... 5
1.1 Preamble ................................................................................................................. 5
1.2 Site Location and Description ...............................................................................5
1.3 Legislative and Other Requirements ....................................................................5
2.0 SURFACE WATER QUALITY .................................................................................6
2.1 Physical Parameters ..............................................................................................6
2.2 Chemical Parameters .............................................................................................6
2.3 Total Petroleum Hydrocarbons .............................................................................7
2.4 Algae _ ............................................................................................................ 7
2.5 Pesticides .............................................................................................................7
3.0 GROUNDWATER QUALITY ...................................................................................7
3.1 Physical Parameters .............................................................................................. 8
3.2 Chemical Parameters ............................................................................................. 8
3.3 Faecal Coliforms ....................................................................................................8
3.4 Total Petroleum Hydrocarbons .............................................................................9
4.0 BIORETENTION SYSTEM MONITORING ..............................................................9
5.0 ROOF WATER REUSE SYSTEM ............................................................................9
6.0 DISCUSSION ..........................................................................................................9
7.0 RECOMMENDATIONS ..........................................................................................10
8.0 LIMITATIONS OF THIS REPORT .........................................................................10
9.0 CLOSURE ........................................................................................................11
10.0 REFERENCES .......................................................................................................11
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APPENDICES
Appendix A - Figures & Diagrams
- Figure 1.0 - Locality
- Figure 2.0 - Aerial
- Drawing DE0923/01
- Drawing DE0923/02
- Drawing DE0923/03
- Drawing DE0923/04
Appendix B - Water Quality Monitoring Summary Results
Table B1 - Surface Water Physical Parameters
Table B2 - Surface Water Chemical Parameters
- Table B3 - Surface Water TPH Results
Table B4 - Surface Water Algae Results
Table B5 - Groundwater Physical Parameters
Table B6 - Groundwater Chemical Parameters
Table B7 - Groundwater TPH Results
Table B8 - Bioretention Basin Results
Table B9 - Roof Water Monitoring Results
Appendix C - Laboratory Reports
I
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1.0 INTRODUCTION
1.1 Preamble
Duke Environmental was commissioned by Stockwell Property Management Pty
Ltd to undertake ongoing water quality monitoring associated with operational
requirements for the Noosa Civic site.
The purpose of this monitoring is to comply with conditions of the Development
Approval for the site, issued by Noosa Shire Council, to demonstrate compliance
with the Noosa Civic Operations Stormwater Management Plan prepared by URS
(Ref: 42605827-RO101C OSWMP) and the Addendum Report prepared by BMT
WBM (Ref: R.B16337.008.01.OSMP Addendum.doc).
In accordance with approval from Council for amendments to the original
monitoring program, Duke Environmental undertook the following monitoring
components:
• Surface Water Quality
• Groundwater Quality
• Bioretention Systems
• Roof Water Reuse System.
Results reported herein are inclusive of the following monitoring periods:
• 2008 - 2009 (Ref: BMT WBM R.131 6337.008.00. Nov 08-NovO9.doc)
• 2009 - 2010
1.2 Site Location and Description
The subject site is located at 28 Eenie Creek Road, Noosaville. The site is
bounded by Eenie Creek Road to the north, existing industrial areas to the west, a
paperbark wetland to the east, extending beyond Walter Hay Drive, and paperbark
wetland to the south, adjoining Eenie Creek.
A Locality Plan (Figure 1.0) and Aerial Photograph (Figure 2.0) are included in
Appendix A.
1.3 Legislative and Other Reguiremen s
The monitoring program is designed to generally comply with the relevant
requirements of the Environmental Protection (Water) Policy 2009 (EPP), stated
requirements of the Local Authority, ANZECC Guidelines for Fresh and Marine
Water Quality (2000), Queensland EPA - Draft Water Quality Guidelines for
Queensland (May 2005), and site specific (Noosa Civic) Water Quality Objectives.
1
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2.0 SURFACE WATER QUALITY
Surface water quality monitoring was undertaken at the following five (5) locations:
• SW1 - located along the western drainage line;
• SW2 - located along the eastern drainage line;
• SW3 - undisturbed reference site in the paperbark wetland;
• SW4 - dam downstream of SW 1; and
• SW5 - wetland downstream of the eastern and western drainage lines.
Refer to Drawings DE0923/01, 03 and 04 included in Appendix A for locations of
monitoring points.
Surface water quality monitoring was undertaken once only (annually) for pesticides,
quarterly for chemical and physical parameters, and quarterly during summer months for
algae, in accordance with the Noosa Civic Operations Stormwater Management Plan
prepared by URS (Ref: 42605827-R0101C OSWMP) and the Addendum Report
prepared by BMT WBM (Ref: R.B16337.008.01.OSMP_Addendum.doc). Refer to
Appendix B for tables of results.
In-situ testing was undertaken using a calibrated Honba U10 Multi Probe meter.
Samples collected were forwarded to a NATA accredited laboratory for testing.
Refer Appendix C for copy of laboratory reports.
2.1 Physical Parameters
Objectives for physical parameters are based on:
• Derived values for Noosa Civic determined during the construction phase
monitoring (suspended sediment).
• Demonstrating that periodic acidic conditions are being maintained to
provide suitable breeding habitat for wallum froglets.
Correlation between pH levels and organic carbon concentrations (and rainfall
data) has been undertaken. In order to maintain breeding habitat for the wallum
froglet, pH levels of <5.5 at least once a year in the paperbark wetland are
necessary. Levels at the reference site (SW3) were at pH4.2 during the drier
months of June 2010 and August 2010.
The median value for suspended solids exceeded Noosa Civic Water Quality
Objectives (WQOs) at all locations except SW2. It should be noted that
significant rainfall (93.8mm) was recorded in the week prior to the January 2010
monitoring event, and that suspended sediment levels at the reference site were
also higher than the WQOs.
Refer to Table 131 in Appendix B for summary of results.
2.2 Chemical Parameters
P_J Chemical objectives are based on:
t •
•
Noosa Civic derived values (nutrients).
Draft Qld EPA (2005) water quality guidelines or ANZECC guidelines as
applicable for heavy metals and pesticide concentrations.
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Total nitrogen exceeded Noosa Civic WQO's at all locations, however all fell
below the median value of the reference site (SW3), indicating the elevated
levels may represent natural fluctuations of the area.
Total phosphorus exceeded Noosa Civic WQOs at SW5. However it should be
noted that levels in the drainage lines leading to SW5 were below the WQOs,
indicating Noosa Civic to be an unlikely source of the elevated levels.
All other chemical parameter results were within defined water quality objectives.
Refer to Table B2 in Appendix B for summary of results.
2.3 Total Petroleum Hydrocarbons
In November 2009, levels of hydrocarbons (C15-C28 fraction -160pg/L, and
C29-C36 fraction - 50pg/L) were detected at SW4 (Dam), however the drainage
lines leading in and out of the dam contained insufficient water to determine a
source of the contamination.
Results from testing in June 2010, indicated levels of hydrocarbons (C10-C14
fraction - 70pg/L, and C15-C28 - 350pg/L) in SW2 (eastern drainage line) and
SW3 (C15-C28 fraction - 160pg/L, and C29-C36 - 90pg/L) (paperbark wetland
reference point, adjacent Eenie Creek). Hydrocarbons were not detected at
I SW5, indicating the contamination from SW2 had not extended beyond the
monitoring point. The drainage line leading to SW2, adjoins the access road
leading into Noosa Civic. SW3 is independent, and located a significant distance
from Noosa Civic, however may capture runoff from Walter Hay Drive.
Hydrocarbons were not detected at any monitoring location during the August
2010 event.
Refer Table B3 in Appendix B for summary of results.
2.4 Algae
Varying levels of algae were detected at all monitoring locations throughout the
sampling period. The highest levels were recorded at SW3 and SW5, both of which
are located within the paperbark wetland. ANZECC water quality guidelines specify
an upper limit of 15,000 cells/mL - 20,000 cells/mL for recreational use. As the highest
reading of 17,500 cells/mL falls within this range and the areas are not utilised for
recreation, we do not consider algae to be a cause for concern.
Refer Table B4 in Appendix B for summary of results.
2.5 Pesticides
Pesticides were below laboratory limits of reporting for all sampling locations.
Refer Table B2 in Appendix B for summary of results.
3.0 GROUNDWATER QUALITY
Groundwater quality monitoring is undertaken at the following two (2) locations:
• GW1 - Downstream of the dam on the western drainage line;
• GW2 - In a vacant allotment to the west of the site (allotment has been
developed into an industrial subdivision, with roadway and kerb and channel
during 2009).
Refer to drawing DE0923/03 included in Appendix A for location of monitoring wells.
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Monitoring was undertaken monthly for physical parameters and biannual for chemical
parameters. Refer to Appendix B for tables of results.
In-situ testing was undertaken using a calibrated Horiba U10 Multi Probe meter, and
Milwaukee SM500 ORP meter. Samples collected were forwarded to a NATA accredited
laboratory for testing.
Refer Appendix C for copy of laboratory reports.
3.1 Physical Parameters
The median pH of groundwater at both wells falls within the desired range for
wallum froglet habitat (i.e. pH below 5.5 at least once annually during prolonged
dry weather). The pH levels remained relatively stable throughout the monitoring
period. It should be noted that GW1 had water levels above the ground surface
levels on several occasions, whilst GW2 was slow to recharge.
Refer to Table B5 included in Appendix B for summary of results.
3.2 Chemical Parameters
Chemical objectives are based on:
• Noosa Civic derived values (nutrients).
• Draft Qld EPA (2005) water quality guidelines or ANZECC guidelines as
applicable for heavy metals and pesticide concentrations
The Noosa Civic derived value water quality objectives for total nitrogen was
exceeded during both monitoring events at both ground water wells. Total
phosphorus was exceeded at GW2 on both occasions; however fell within the
WQO at GW1 during the June 2010 monitoring event. It should be noted that
nitrogen also exceeded Noosa Civic WQOs at all surface water monitoring points
and phosphorus levels were exceeded at SW5 indicating the elevated levels may
represent natural fluctuations and background levels of the area.
Dissolved zinc, aluminium and copper exceeded ANZECC guidelines at GW1
and GW2. All other parameters fell within guidelines. Locally derived values were
established by BMT WBM (Ref: R.B16337.008.00.NovO8-NovO9.doc) based on
data collected from SW3 (Wetland reference site) during construction phase
monitoring. Aluminium and copper levels fall within these WQOs, however zinc
exceeded these WQOS (0.113mg/L) during the June 2010 sampling event.
Further monitoring is required to determine if these levels are a result of natural
fluctuation or external contamination.
Refer to Table B6 included in Appendix B for summary of results.
3.3 Faecal Coliforms
Levels of faecal coliforms were detected at GW1 (38cfu/lOOmL) and GW2
(320cfu/100mL) during the June 2010 sampling event, however limits for faecal
coliforms in aquatic ecosystems have not been set by ANZECC. Limits for
recreational use are set at 150cfu/100mL for primary contact and 1000cfu/100mL
for secondary contact. As primary and secondary contact do not occur with the
groundwater we do not consider this to be a health risk. Faecal indicator
organisms are derived from a range of sources including industrial processes,
wildlife, domestic animals and sewage effluent. Previous results were
<10cfu/100mL, therefore we recommend that results from the next round of
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testing be utilised to determine if further investigation is required, or if this was an
isolated event.
Refer to Table B6 in Appendix B for summary of results.
3.4 Total Petroleum Hydrocarbons
All results were below laboratory limits of reporting. Refer to Table B7 included in
Appendix B for summary of results.
1 4.0 BIORETENTION SYSTEM MONITORING
In accordance with commissioning, the bioretention basins were tested once only,
following a significant rainfall event. Sampling was undertaken at the following locations,
based on information contained within MBT WBM OSWMP - Addendum Report, which
indicated that only these locations provide access and unmixed water:
• BR1/2A;
• BR 1 /213; and
• BR1/3A;
I Sampling was not undertaken at BR1/3B, due to water flow not observed from the outlet.
The issue was reported to Noosa Civic Management and we understand that
maintenance was undertaken. Refer to Table B8 in Appendix B for summary of results.
Permeability testing and soil contamination testing are not required until the end of year
5. Photographic survey was not within the scope of this commissioning.
Fil
5.0 ROOF WATER REUSE SYSTEM
The roof water collection tanks were inspected on a quarterly basis. Refer to Drawing
DE0923/03 for location of inspection points.
Observations are summarised in Table B9 in Appendix B.
The presence of mosquito and cane toad larvae was not detected during inspections. Sludge
within the tanks was immeasurable. A small quantity of floating litter was observed during the
inspection in November 2009 and February 2010. Advice received from Noosa Civic
I Management indicated that the tanks had been leaned out prior to the inspection in
September 2010. The concrete bottom of the tank was clearty visible during this inspection,
with only a very minor amount of leaf litter observed within the tank.
6.0 DISCUSSION
As a result of the significant increase of developed land in the vicinity of the Noosa Civic,
we consider that the monitoring points specified under the OSMP may no longer be
indicative of runoff quality independent to the complex.
As such, we consider a review of monitoring locations and WQOs should be undertaken.
The area surrounding the site is now largely developed with additional roads, and
several of the monitoring locations have catchments which are no longer exclusive to
Noosa Civic.
In addition we consider dissolved oxygen parameters designed for flowing waters are
generally not applicable in this instance and should be amended in line with median
values obtained over the last 12 months of monitoring.
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The location of GW2 is now the site of an industrial subdivision. In the event that the
allotment on which it is located is purchased and developed, this monitoring bore may no
longer be available.
1 We note that alterations of monitoring locations may adversely affect the previously
determined median values (as WQOs). As such, we would consider it inappropriate to
designate new monitoring points. Therefore, we would recommend that the water
monitoring program reduce the number of monitoring points to those receiving runoff
strictly relative to Noosa Civic.
1 Quarterly inspections of the roof water collection tanks indicated that mosquito and cane
toad larvae were not present, nor were the levels of sludge measurable. The interior of
the tanks appeared clean and well maintained.
1
7.0 RECOMMENDATIONS
We provide the following recommendations based on the monitoring undertaken to date:
1 •
•
Reduce number of monitoring locations to those which receive runoff strictly
exclusive to Noosa Civic.
Review relevance of Water Quality Objectives, (particularly dissolved oxygen).
• Elimination of GW2 from the monitoring program.
• Reduce water tank inspections to bi-annual.
• Utilise results from the next round of groundwater testing to determine if further
investigation of faecal coliform contamination is required, or if this was an
isolated event.
8.0 LIMITATIONS OF THIS REPORT
This Water Quality Monitoring Report has been tailored to report on issues in the area of
interest, as detailed above. The information in this report is not to be used outside of the
subject area.
We consider that this report accurately considers conditions at the area of interest at the
time the testing was undertaken and the report was compiled, and based on information
supplied to us by second and third parties.
This report has been undertaken for the specific purposes of Stockwell Property
Management Pty Ltd, as detailed in our correspondence to them, and is solely for the
use of Stockwell Property Management Pty Ltd.
This report should only be used in full, and may not be used to support objectives other
than those set out herein, except where written approval, with comments, are provided
by Duke Environmental.
Duke Environmental accept no liability with respect to the accuracy of information
supplied by second and third parties.
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9.0 CLOSURE
This report has been commissioned by Stockwell Property Management Pty Ltd
specifically for the Environmental Monitoring at Noosa Civic.
Stephen Hayes
BSc(Env) Hons CEnvP MEIANZ
Senior Environmental Scientist / Ecologist
For Duke Environmental
2011
10.0 REFERENCES
1.0 BMT WBM, 2008. Noosa Civic Operations Stormwater Management Plan -
Addendum Report (Ref: R.816337.008.01.OSMP_Addendum.doc) Spring Hill,
Qld.
2.0 Environmental Protection Act 1994.
3.0 Environmental Protection (Water) Policy 2009.
4.0 National Health and Medical Research Council, 2008, Guidelines for Managing
Risks in Recreational Water, Australian Government, Canberra.
5.0 URS, 2006. Noosa Civic Operations Stormwater Management Plan (Ref:
42605827-RO 101 C OSWMP).
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'APPENDIX
A
FIGURES AND
DIAGRAMS
t
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APPENDIX
A
FIGURES AND
DIAGRAMS
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m m m m m m m m m m m m m m m m m m m m m
Page 18
Noosa
Shire I
Business
Centre
DUKE ENVIRONMENTAL
NOT TO SCALE
LOCALITY - FIGURE 1.0
Subject Site DE0923
Page 19
DUKE ENVIRONMENTAL
NOT TO SCALE
AERIAL - FIGURE 2.0
Subject Site DE0923
[OCR of page images]
DUKE ENVIRONMENTAL
NOT TO SCALE
| , AERIAL - FIGURE 2.0
Subject Site * DE0923
Page 20
NOOSA CIVIC OPERATIONAL WATER
QUALITY MONITORING
28 EENIE CREEK ROAD, NOOSAVILLE
SITE OVERVIEW
KEY
MONITORING LOCATION
3.OG- NATURAL CONTOUR LINE
DRAINAGE LINE! WATERWAY
BUILDING
I BIO-RETENTION BASIN
I
APPROVED DOCUMENT STATUS P! 07 5483 3371 CU ENT STOCKWELL
Design: S.H.
F 07 5493 3422
Drawn. S.H. FOR APPROVAL E [email protected] PROJECT NOOSA CIVIC OPERATIONAL WATER QUALITY MONITORING
(Not for Construction) PO Box 78 Wurhrlla 4575 Sheet I of 4
Date 02-12-09 AT 28 EENIE CREEK ROAD, NOOSAVILLE
Survey By: Powerful Owl Qld Pry Ltd LOT 1 ON RP215933 & LOT 2 ON SP1 10885 DRAWING No:
Datum AHD. SIZE A3 FILE WATER QUALITY MONITORING LOCATIONS DE0923/01
Page 21
KEY
e MONITORING LOCATION
--3.00- NATURAL CONTOUR LINE
DRAINAGE UNE I WATERWAY
BUILDING
BIO-RETENTION BASIN
MONITORING LOCATIONS
SPECIFIED IN ACCORDANCE
WITH URS NOOSA CIVIC
OPERATIONAL STORMWATER
MANAGEMENT PLAN DATED 26
AUGUST 2006.
Design: S.H. APPROVED DOCUMENT STATUS P 07 5493 3322 CLIENT STOCKWELL
c 07 5493 3422
FOR APPROVAL E de@dukerxlro oom,au PROJECT NOOSA CIVIC OPERATIONAL WATER QUALITY MONITORING
Drawn: S.H.
(Not for Construction) f ur
PQ Box 78 Wurtulla 4575 AT: 28 EENIE CREEK ROAD, NOOSAVILLE
Dale 02-12-09
I Survey By' - Powerful Owl Qld Ply Ltd LOT 1 ON RP215933 & LOT 2 ON SP 110885
TA Duke Emsrorne: ;^l
DRAWING No:
' Checked PD DATE
Datum AHD F7777 -73 TITLE WATER QUALITY MONITORING LOCATIONS DE0923/02
Page 22
KEY
MONITORING LOCATION
-3.00 NATURAL CONTOUR LINE
DRAINAGE LINE 1 WATERWAY
BUILDING
BIO-RETENTION BASIN
MONITORING LOCATIONS
SPECIFIED IN ACCORDANCE
WITH URS NOOSA CIVIC
OPERATIONAL STORMWATER
MANAGEMENT PLAN DATED 26
AUGUST 2006.
I
APPROVED DOCUMENT STATUS P 07 5493 3322 STOCKWELL
Desgn: S.H. F 07 5493 3422
FOR APPROVAL PROJECT NOOSA CIVIC OPERATIONAL WATER QUALITY MONITORING
Drawn: S.H.
(Not for Construction)
E [email protected]
PO Box 78 Wurtulla 4575
uu iw AT 28 EENIE CREEK ROAD, NOOSAVILLE Sheet 3 of 4
Date 02-12-09
Survey By: - Powerful Owl Old Ply Ltd PYi'nr LOT 1 ON RP215933 & LOT 2 ON SP110885 DRAWING No:
Checked. P.D T A Doke Envronmen*3 Lnv,,onn:enlvl M
Dawn, AND SIZE A3 7MS PIA! rS COPYRIGHT PK TITLE WATER QUALITY MONITORING LOCATIONS DE0923103
Page 23
V
MONITORING LOCATION
3.00 NATURAL CONTOUR LINE
DRAINAGE LINE 1 WATERWAY
BUILDING
BIO-RETENTION BASIN
MONITORING LOCATIONS
SPECIFIED IN ACCORDANCE
WITH URS NOOSA CIVIC
OPERATIONAL STORMWATER
MANAGEMENT PLAN DATED 26
AUGUST 2006.
1 REFER REPORT FOR
CO-ORDINATES OF SW3
P Q754333 22 CLIENT STOCKWELL
Design: S.H. APPROVED DOCUMENT STATUS
F 07 5493 $422
Drawn S.H. FOR APPROVAL E [email protected] PROJECT NOOSA CIVIC OPERATIONAL WATER QUALITY MONITORING
(Not for Construction) PD Box 78 Wurtulia 4575 Sheet 4 of 4
Date 02-12-09 AT 28 EENIE CREEK ROAD, NOOSAVILLE
Survey By: - Powerful Owl Old Pry Lid LOT 1 ON RP215933 & LOT 2ON SP110885 DRAWING No:
Checked P. D.
Datum: A H D 1 S17F A3 TITLE WATER QUALITY MONITORING LOCATIONS DE0923,%04
Page 24
APPENDIX
WATER QUALITY
MONITORING
SUMMARY RESULTS
1
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APPENDIX
B
WATER QUALITY
MONITORING
SUMMARY RESULTS
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Page 26
Surface Water Physical Parameters
Table B1
Electrical Dissolved Dissolved
pH Conductivity Turbidity Oxygen Oxygen Temperature Rainfall Revious 24
NS/cm NTU mg/L- % °C hours
SW1
Date
23.1 1109 Its Is is I's I's Is 0
1201110 73 740 38 6 79 29.8 0
03/03/10 63 190 15 3 35 23.1 103
01/06/10 6.1 220 7 4.4 42 18.9 0
16 08.10 6.1 266 17 6.1 64 176 0
Median 6.3 231 17 5.1 62 23.1 0
SW2
Date
231 1.09 Its L'S US I s I/s Us 0
1210110 7.3 200 8 3.2 42 28 0
03/03/10 6.4 190 23 3.3 40 24.4 103
01/06/10 5.8 220 8 3.6 37 17.2 0
16,08/10 5.9 500 3 3.7 40 183 0
Median 6.4 210 8 3.6 40 24.4 0
SW3
Date
23/11/09 I/s I/S I/s Vs I/s I/S 0
12/01110 691 240 44 1.4 16 25.4 0
03/03/10 5.2 90 11 1.8 20 23.8 103
01/06/10 4.2 380 9 3.2 34 19.4 0
16/08/10 4.2 480 26 3.8 39 16 6 0
Median 5.14 240 11 3.2 34 23.8 0
SW4
Date
23/11/09 6.2 260 15 494 50 22.8 0
12/01/10 N/S N/S N/S N/S N/S N/S N/S
03/03/10 6 740 20 1.1 12 2394 103
01 /06/10 598 130 16 3.2 36 204 0
16108/10 61 260 7 10.6 115 21.9 0
Median 6.1 260 16 4.4 50 22.8 0
SW5
Date
23/11/09 l's l's Ls Us L's is 0
1201/10 64 240 44 194 16 25.4 0
03/03/10 63 110 13 2.6 30 235 103
01/06'10 5.9 160 2 3.2 34 18.4 0
16108+'10 5.7 200 55 4.2 42 15.9 0
Median 5.9 197 26.3 3.2 34 23.4 0
Denved Value <5.5
(once a year)
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23/11/09
12/01/10
03/03/10
01/06/10
16/08/10
Median
TERT,
23/11/09
12/01/10
03/03/10
01/06/10
16/08/10
Median
19/11/08
23/11/09
12/01/10
03/03/10
01/06/10
16/08/10
Median
vT4
23/11/09
12/01/10
03/03/10
01/06/10
16/08/10
Median
19
23/11/09
12/01/10
03/03/10
01/06/10
16/08/10
Median
Derived Value <5.5
(once a year)
AE0923WQM
March 2011
SHijs
urf Water Physical Parame
Table B1
a ee -
Page 27
Surface Water Chemical Parameters
Table 52
Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved
Total N TKN Nitrite as N Nitrate as N Total P DOC SS Hardness As Cd Cr Cu Ni Pb Zn OC/OP Reactive P
(mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (yg/L) (mg/L)
swi
Date
23111!09 Us Is I/s Its I!s Us 's Its 11s Us I's I/s I's i/s is Its Ih
12/01/10 22 21 <001 0.1 0 24 11 27 135 <0 001 00001 <0001 0.009 0 004 <0.001 0 12 <LOR <001
03/03/10 07 06 -001 008 0 03 14 <5 51 <0 001 0.0001 0.001 0.004 0.001 <0.001 0.044 NT <0.01
02/06/10 1 09 001 007 <0 01 4 5 58 <0.001 <0.0001 <0.001 0.002 <0 001 <0.001 0.02 NT <0.01
16.08'10 03 02 '001 not 0 03 4 <5 62 <000' <0.0001 <0.001 <0.001 <0.001 <0.001 0018 NT <001
Me(1 0.85 0.75 <0.01 0.075 0.03 7.5 16 60 <0.001 0.0001 0.001 0.004 0.0025 <0.001 0.032 <LOR <001
SW2
Date
23111/09 Its Its I/s Its Its I/s Its Its I's Its Its 2s 2< Its I/$ Its Its
12/01110 1 1 1 1 <0 01 0 02 0 19 11 <5 70 0.001 <0.0001 <0,001 0003 0.001 <0.001 0.044 <LOR <0.01
03/03110 09 06 <0.01 0 28 0 02 14 <5 49 <0.001 0.0001 0.001 0004 <0 001 <0 001 0029 NT <0.01
02/06110 04 02 <0.01 0 15 <0.01 7 9 91 <0 001 <0.0001 <0.001 0.002 <0 001 <0.001 0026 NT <0.01
11,08110 05 04 .001 0 13 002 7 5 211 < 000' 100001 -0001 0.002 <0 001 <0.001 002 NT <001
Median 0.7 0.5 <0.01 0.14 0.02 9 <5 80.5 0.001 0.0001 0.001 0.0025 0.001 <0.001 0.0275 <LOR <0.01
SW3
Date
23, 110) Its Its Its Its I's Its 1s <S Us Its Iis Us s I!5 Its I;s Iis
12101110 1 5 1 5 -001 0.03 048 7 35 4950 <0.050 <0.0005 0.005 <0.050 '0050 <0.005 <0 050 <LOR <001
03/03/10 1 09 -001 0.1 002 26 5 14 <0.001 0.0002 <0.001 0002 <0 001 <0.001 0 033 NT <0.01
02/06/10 14 1 4 -001 0 02 004 17 53 64 <0.001 0.0001 <0.001 0.004 0 001 <0 001 0 015 NT 001
7 587, 04 04 <0 01 001 0 02 10 5 72 <0 001 <0.0001 <0.001 <0.001 0 002 <0.001 002 NT
701
Median 1.2 1.15 <0.01 0.025 0.03 13.5 20 68 <0.001 0.00015 <0.001 0.003 0.0015 <0.001 0.02 <LOR <0.01
SW4
Date
1.11 I I U9 08 07 <001 UI - 0 I 14 23 77 <0.001 <0.0001 <0 001 0 602 <0 0'71 <0.001 001 <LOR <001
12/01/10 NIS N/S N/S N/S N/S N/S NIS NiS N/S N/S N'S N/S N/S N/S N/S WS N/S
03/03110 06 06 <0.01 0 02 0 04 11 <5 17 <0.001 00002 <0 001 0002 <0 001 <0 001 0 016 NT 0 02
02/06/10 02 0.2 <0.01 0 02 0 02 6 9 38 <0.001 <0.0001 <0 001 <0.001 <0 001 <0.001 <0 005 NT 001
16/08/10 02 0.2 <001 0 02 001 6 <5 64 <0 001 <0.0001 <0 001 0001 <0 001 <0 001 0 016 NT <001
Median 0.4 0.4 <0.01 0.02 0.02 8.5 16 51 <0.001 0.0002 <0.001 0.002 <0.001 <0.001 0.016 <LOR <0.01
AE0923WOM
March 2011
SH(s
[OCR of page images]
23/11/09
12/01/10
03/03/10
02/06/10
1 a
Median
211)
12/01/10
03/03/10
02/06/10
16/08/11
edian
23/11/09
12/01/10
03/03/10
02/06/1
16/08/10
Median
2411/09
12/01/10
03/03/10
02/06/10
16/08/10
edian
AEO923WQM
March 2011
SH/js
Total N
(mg/L)
TKN
(mg/L)
Nitrite as N | Nitrate as
(mg/L)
(mg/L)
Surface W ater Chemical Parameters
Table B2
0014
l/s
<0.050
<0.001
<0.001
<0.001
<0.001
V/s
0.0001
0.0001
<0.0001
<0.0001
V/s
<0.0001
1
1
<0.001
7
Page 28
Surface Water Chemical Parameters
Table B2
Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved
Total N TKN Nitrite as N Nitrate as N Total P DOC SS Hardness As Cd Cr Cu Ni Pb Zn OC/OP Reactive P
(me/L) (mfl/LI (m9 /L) (m9/L) ( m9/L) Im9/Ll (m0/LI (m9 /L) (m9/L) (m9/LI (mg/L) (m9/L) (m 9/L) (me/L) (m9/L) ;/L) ( m9/L)
SW5
Date
2_i 11'. P,i I.S I$ I s I S its its Its Its Its Its I's Ih us I/S
12r'C1'o 29 28 -001 006 04 13 69 57 0002 0001 0001 0008 0001 <0001 0021 <LOR •001
03/03/10 05 05 -001 0.04 009 12 <5 29 <0001 00002 <0001 0002 <0001 <0001 0017 NT <001
0210610 03 03 .001 0.02 0 09 10 13 40 <0.001 <0 0001 '0001 0 001 -0001 • 0 001 0006 NT <0.01
16108110 04 0.4 '001 0 03 0 09 9 19 47 <0.001 <0 0001 <0 001 '0001 -0001 '0001 0009 NT '001
Median 0.45 0.45 <0.01 0.035 0.09 11 19 43.5 0.002 0.00015 0.001 0.002 0.001 <0.001 0.013 <LOR <0.01
Water quality objectives
Noosa Civic -05 -005 <15 0.006 0.0016 0 113
AN!_ L G (: 05 07 - 0.024 0.0002 0.001 00014 0011 0.0034 0008 0 02
EPP WOO's .05 <0.05
AE0923WOM
March 2011
SH/s
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Surface W ater Chemical Parameters
Table B2
Hardness | As
(mg/L) | (mg/L)
11/09
12/01/10
10
02/06/10
16/08/10
Median
0.006
0.0014 0.011
AEO0S23WQM
March 2011
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Page 29
Surface Water Total Petoleum Hydrocarbons
Table B3
TPH C6-C9 C10-C14 C15-C28 C29-C36
(NgIL) (N9IL) (N92) (NgIL) (NgIL)
swi
Date
23/11/09 I/s I/s I/s I/s I/s
12/01/10 <50 <20 <50 <100 <50
03/03/10 <50 <20 <50 <100 <50
02/06/10 <50 <20 <50 <100 <50
16/08/10 <50 <20 <50 <100 <50
Median <50 <20 <50 <100 <50
SW2
Date
23;11.09 I/s I/s I/s I/s I/s
12/01/10 <50 <20 <50 <100 <50
03/03/10 <50 <20 <50 <100 <50
02/06/10 420 <20 70 350 <50
16/08/10 <50 <20 <50 <100 <50
Median 420 <20 55 192 12
SW3
Date
23/11/09 I/s I/s I/s I/s I/s
12/01/10 <50 <20 <50 <100 <50
03/03/10 <50 <20 <50 <100 • 50
02/06/10 250 <20 <50 160 90
16/08/10 <50 <20 <50 <100 <50
0
Median 250 <20 <50 160 90
SW4
Date
23111i09 210 <20 <50 160 50
12/01/10 N/S N/S N/S N/S N/S
03/03/10 <50 <20 <50 <100 <50
02/06/10 <50 <20 <50 <100 <50
16/08/10 <50 <20 <50 <100 <50
Median 210 <20 <50 160 50
SW5
Date
23/11/09 I/s I/s I/s I/s I/s
12/01/10 <50 <20 <50 <100 <50
03/03/10 <50 <20 <50 <100 <50
02/06/10 <50 <20 <50 <100 <50
16/08/10 <50 <20 <50 <100 <50
Median <50 <20 <50 <100 <50
Shaded cells indicate exceedance
AEO923W QM
March 2011
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Surface Water Total Petoleum Hydrocarbons
Table B3
TPH cé-c9 | C10-C14 | C15-C28 | C29-C36
(ug/L)
12/01/10
03/03/10
0
0
na
V/s
<
<50
< <
1 0 <50 <
Median <50 <20
Shaded cells indicate exceedance
AE09S23WQM
March 2011
SH/js
Page 30
Surface Water Algae
Table B4
Location Total Total Total Total Total Dinoflagellates
I -
& Date
Total Cyanophytes
(Cells/mL)
Chlorophytes
(Cells/mL)
Flagellates
(Cells/mi)
Chrysophytes
(Cells/mL)
Diatoms
(Cells/ml.) (Cells/mL)
swi
23/11/09 I/s I/s I/s I/s I/s NT
12/01/10 120 <1 40 <1 80 NT
03/03/10 ND 5 ND NT ND ND
15/09/10 120 ND ND NT 520 NT
Median 120 5 40 <1 300 NT
23/11/09 Is Its I/s I/s I/s NT
U 12/01/10
03/03/10
15/09/10
40
ND
60
30
10
ND
20
ND
ND
<1
NT
NT
130
ND
1640
NT
ND
NT
Median 50 20 20 <1 885 NT
SW3
1 23/11/09
12/01/10
03/03/10
I/s
3600
350
I/s
<1
5
I/s
<1
5
I/s
<1
NT
I/s
NT
ND
NT
NT
ND
U Vwr
15/09/10
Median
740
688.5
3230
289
6350
3177.5
NT
17
17500
8757.5
NT
NT
! 11
23/11/09 7420 360 240 20 260 NT
12/01/10 NS NS NS NS NS NT
t 03/03/10
15/09/10
Median
200
ND
442
35
150
150
60
ND
60
NT
NT
20
45
5800
152.5
25
NT
25
SW5
U) j
23/11/09 I/s I/s I/s I/s I/s NT
12/01/10 4300 700 7000 ND 2000 NT
03/03/10 ND 55 70 NT 20 ND
15/09/10 740 ND ND NT 7180 NT
Median 740 102 170 NT 2000 NT
I/s = Insufficient sample available
ND = Not detected by laboratory
NS = Not Specified
NT = Not Tested
ANZECC values for recreational use - 15,000-20,000 cells/mL
AL0923WQM
March 2011
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1
Page 31
Groundwater Physical Parameters
Table B5
Rainfall
Electrical Dissolved Redox Previous 24
Date Conductivity Level' Oxygen Potential Temp hours
H (NS/cm) (mBGL) (mg/L) (mV) (C) (mm)
GWI
23/11/09 5.1 751 2.48 5.3 286 22.9 0
06/12/09 5 327 2 3.6 252 23.6 0
12/01/10 6.2 265 0.68 2.1 223 23.9 0
09/02/10 6.8 96 0 3.2 140 24.9 16.2
03/03/10 5.7 260 0.17 asl 2.7 108 24 103
12/04/10 5.3 192 0.10 asl 0.9 173 23.2 7.6
02/06/10 5.4 323 0.01 asl 2.8 130 19.3 0
15/07/10 5.7 291 0.29 2.7 171 18.5 0
16/08/10 5.4 276 0.07 asl 3.1 127 17.3 0
15/09/10 5.9 210 0.09 2.9 155 19.4 0
18/10/10 5.6 243 0.06 asl 3.1 65 19.5 0
Median 5.6 265 0.485 2.9 155 22.9 0
IdW2
23/11/09 5 175 3.13 I/s 180 25.3 0
06/12/09 5.2 162 3.01 2.2 203 25.5 0
12/01/10 5.3 188 2.08 2.6 264 25.8 0
09/02/10 6.1 103 0.29 3.3 207 27.4 16.2
03/03/10 5.4 134 1.2 1.9 -44 25.6 103
12/04/10 4.7 125 0.11 0.2 141 25.5 7.6
02/06/10 5.2 112 0.87 3.9 210 22.8 0
15/07/10 5.3 113 1.62 5.7 179 20.2 0
16/08/10 5.2 182 1.17 3.6 180 21.9 0
15/09/10 5.4 166 1.58 4.7 207 22.7 0
18/10/10 5.2 200 0.6 3.8 126 23.2 0
Median 5.2 162 1.2 3.45 180 25.3 0
*asl - above surface level
I/s - insufficient to sample
Derived WQOs
<5.5 at least once per year
AE0923W QM
March 2011
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Groun ter Physical Parameters
Table BS
Date
12/01/09 5.3 < 0.12
23/11/09 5.1 2.48
06/12/09 5 2
12/01/10 6.2 0.68
09/02/10 6.8 0
03/03/10 5.7 0.17 asl
12/04/10 5.3 0.10 asl
02/06/10 5.4 0.01 asl
15/07/10 5.7 0.29
16/08/10 5.4 0.07 asl
15/09/10 5.9 0.09
18/10/10 5.6 0.06 asl
Median 5.6 0.485
12/01/09 4.43 1.34
23/11/09 5
06/12/09 5.2
12/01/10 5.3
09/02/10 6.1
03/03/10 5.4
12/04/10 47 125
02/06/10 5.2 1
15/07/10 5.3 113
16/08/10 5.2
15/09/10 5.4 166
18/10/10 5.2
Median 5.2 162
“asl - above surface level
I/s - insufficient to sample
Derived WQOs
<5.5 at least once per year
AE0923WQM
March 2011
SHijs
Page 32
Groundwater Chemical Parameters
Table B6
Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Faecal
Total N TKN Nitrite as N Nitrate as NJ Total P Al Fe As Cd Cr Cu NI Pb Z. Coliforms Reactive P
(mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mgIL) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (cfu/100mL) (mgIL)
GW1
Date
23,11 09 22 2.1 0 11 06 0 07 0.07 '300' 0008 <0.001 0007 0.005 <0 001 095 <10 <0 01
120110 NS NS NS NS NS NS N'S N,S NS N/S NIS NIS NS NS NS NS
02 06 1' 77 0.6 <0 01 0 09 67 <0001 0002 <0 001 0 002 0002 <0 0' ' 38 <0.01
Median 1.45 1.35 <0.01 0.1 0.325 0.145 0.87 0.001 0.0005 <0.001 0.0045 0.0035 <0.001 2.5125 38 <0.01
GW2
Date
2311;09 5 .4 5.2 I/s I/s 0.38 0.26 2 33 0.002 <0.0001 0.001 0.002 0.002 <0.001 0.081 <10 Iis
1210110 N'S N/S 0.03 2.95 NIS N'S NIS N'S NIS WS NIS NIS N'S N+S NIS <0.01
.
02/06.10 3 1.1 <0.01 0,01 23 , 0 17 <0 001 0.0002 <0.001 0.002 0.001 <0.00 U 147 320 <0.01
Median 3.35 3.15 0.03 1.48 0.305 0.29 1.25 0.002 0.0002 0.001 0.002 0.0015 <0.001 0.114 320 <0.01
Water qua lity objectives - shaded cells ind icate exceedance
Noose Civic 0.5 0.05
ANZECC <0.005 1 0.05 0.0002-0.002 0.01 0.002-0.005 0.015.0.15 0.001-0.005 0.005-0.05
EPP'/"OO 0.02
AE0923WQM
March 2011
SH/js
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Groundwater Chemical Parameters
Table B6
11/09
12/01/10
02/06/1
Median
23/11/09 5.2
12/01/10 /
0 A 1.1 1 01
Median [| P 3.15 0.03 1.48
1 1
0.0015 <0.001
- shaded cells indicate exceedance
0.05
0.002-0.005 | 0.015-0,15 | 0.001-0.005} 0.005-0.05
AE0923WQM
March 2011
SHijs
Page 33
Groundwater Total Petroleum Hydrocarbons
Table B7
TPH C6-C9 C10-C14 C15-C28 C29-C36
(NgIL) (N9/L) (Ng/L) (N9IL) (NgIL)
GW1
Date
23/11/09 <50 <20 <50 <100 <50
02/06/10 < < < < <
Median <50 <20 <50 <100 <50
GW2
Date
23/11/09 US s s s s
12/01/10 < < < < <
1 02/06/
Median
<50
<50
<
<20
<50
<50
<
<100
<
<50
AE0923WQM
' March 2011
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[OCR of page images]
Groundwater Total Petroleum Hydrocarbons
Table B7
AE0923WQM
March 2011
SHijs
Page 34
Big-Retention Basins Physical and Chemical Analysis Results
Table B8
BR1/2A BR1/2B BR1/3A WQO
DATE 02/03/10 02/'03110 02/03/10
pH 4.2 5.2 5.1
Dissolved Oxygen ppm
Electrical Conductivity ps/cm 0.039 0.024 0.018
Turbidity NTU 4 13 9
Total N mg/L 0.4 0.4 0.3 0.05
TKN mg/L 0.4 0.2 0.3
Nitrite as N mg/L <0.01 <0.01 <0.01
Nitrate as N mg/L <0.01 0.23 0.04 0.7
Ammonia as N mg/L 0.05 <0.01 0.06 0.02
Total P mg/L 0.07 0.04 <0.01 0.05
Dissolved Al mg/L 0.07 0.1 0.03
Dissolved Hg mg/L <0.0001 <0.0001 <o.oool
Dissolved As mg/L <0.001 <0.001 <0.001 0.024
Dissolved Cd mg/L 0.0002 0.0002 0.0002 0.0002
Dissolved Cr mg/L <0.001 <0.001 <0.001 0.001
Dissolved Cu mg/L 0.003 0.002 0.002 0.006
Dissolved Ni mg/L <0.00 1 <0.001 <0.001 0.011
Dissolved Pb mg/L >0.001 <o.oo1 <0.001 0.0016
Dissolved Zn mg/L 0.031 0.021 0.023 0.113
Total Hardness as CaCO3 mg/L 20 4 2
Reactive P mg/L <o.o1 <0.01 <0.01 0.02
Dissolved Organic Carbon mg/L 4 2 3
BTEX Below LOR Below LOR Below LOR
PAH Below LOR Below LOR Below LOR
TPH C6-C9 pg/L <20 <20 <20
TPH C10- C14 pg/L <50 <50 <50
TPH C15-C28 pg/L <100 170 <100
TPH C29-C36 pg/L <50 50 <50
LOR = Laboratory limit of reporting
Shaded results indicate exceedance
AE0923WQM
March 2011
SH/js
Page 35
Roof Water Collection Tank Observations
Table B9
Date Hatch Parameter Method Observations
23/11/09 North Sludge Depth Measuring stick Sludge depth was not observable on
measuring stick. Thus. we consider
minimal sludge/sediment to be
present. Some floating litter and debris
observed.
Vermin Spotlighting Cane toads and/or other vermin not
Infestation observed in inlets or elsewhere in
tank. Mosquito larvae not evident on
or near water surface.
Bucket Sample Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
23/11/09 South Sludge Depth Measuring stick Sludge depth was not observable on
measuring stick. Thus, we consider
minimal sludge/sediment to be
present. Moderate amount of floating
litter and debris observed.
Vermin Spotlighting Cane toads and/or other vermin not
Infestation observed in inlets or elsewhere in
tank. Mosquito larvae not evident on
or near water surface.
Bucket Sample Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
09/02/10 North Sludge Depth Measuring stick Sludge depth was not observable on
measuring stick. Thus, we consider
minimal sludge/sediment to be
present. Moderate amount of floating
litter and debris observed.
Vermin Spotlighting Cane toads and/or other vermin not
observed in inlets or elsewhere in
Infestation
1 Bucket Sample
tank. Mosquito larvae not evident on
or near water surface.
Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
09/02/10 South Sludge Depth Measuring stick Sludge depth was not observable on
measuring stick. Thus, we consider
minimal sludge/sediment to be
present. Moderate amount of floating
litter and debris observed.
Vermin Spotlighting Cane toads and/or other vermin not
Infestation observed in inlets or elsewhere in
tank. Mosquito larvae not evident on
or near water surface.
Bucket Sample Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
15/09/10 North Sludge Depth Visual Concrete bottom of tank clearly visible.
Debris or litter not observed.
Vermin Spotlighting Cane toads and/or other vermin not
Infestation observed in inlets or elsewhere in
tank. Mosquito larvae not evident on
or near water surface.
Bucket Sample Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
AE0923WQM Page 1 of 2
March 2011
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Page 36
Date Hatch Parameter Method Observations
15/09/'10 South Sludge Depth Measuring stick Sludge depth was not observable on
measuring stick. Bottom of tank
visible. Thus, we consider minimal
sludge/sediment to be present. Minor
amount of floating leaf litter observed.
Vermin Spotlighting Cane toads and/or other vermin not
Infestation observed in inlets or elsewhere in
tank. Mosquito larvae not evident on
or near water surface.
Bucket Sample Mosquito larvae not observed in
bucket sample. Tadpoles not
observed in bucket sample.
AE0923WQM Page 2 of 2
March 2011
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Page 37
APPENDIX
C
LABORATORY
REPORTS
AE0923WQM
March 2011
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APPENDIX
C
LABORATORY
REPORTS
Page 38
= m = m = m m m = w = = m = = = = = m m m
Page 39
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division ALS
CERTIFICATE OF ANALYSIS
EB0918529 Page 1 of 6
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia 4053
WURTULLA QLD, AUSTRALIA 4575
E-mail [email protected] E-mail [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 OC Level : NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Order number 291821
C-O-C number Date Samples Received 24-NOV-2009
Sampler SH slue Date 02-DEC-2009
ado Noosa Civic
No. of samples received
Quota number BN/317/09 No. of samples analysed 3
This report supersedes any previous report(s) with this reference Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for
release
This Certificate of Analysis contains the following information:
• General Comments
• Analytical Results
• Surrogate Control Limits
NATA Accredited Laboratory 825 Signatories
This document has been electronically signed by the authorized signatories indicated below, Electronic signing has been
NATA This document is issued in
accordance with NATA
carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Position Accreditation Category
accreditation requirements.
Kim McCabe Senior Inorganic Chemist Inorganics
Accred led for compliance wdh
Sarah Ashworth Organic Chemist Organics
ACCREDITATION ISO IEC 17025
Enulronrmcntzl Dlulslon Brisbane
Part of rhd ALS Laboratory Group
32 Shand Street Stafford QLD dustra.-r^
Tel.+61.7.32437222 Fax +61-7-32437218 H,,,, .d„p„onLCOm
Page 40
Page 2 of 6
Work Oidoi EB0918529
Client DUKE ENVIRONMENTAL
Prnlec: DE0923
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR. this may be due to primary sample extract/dgestate dilution and/or insuffient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content. insufficient sample (reduced weight employed) or matrix interference.
When dale(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client.
Key : CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
= Thus result is computed horn ii di. i'Jual analyte detections at or above the level of reporting
• MW006 is ALS's internal code and is equivalent to AS4276.7.
Page 41
Page 3 of 6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923
ALS
Sub-Matrix: WATER Client sample lD F- GW 1 i GW 2 I -SW 4
Client sampling date / time 23-NOV-2009 15:00 23-NOV-2009 15:00 23-NOV-2009 15:00
LOR Unit 1 EB091852S.001 EB0918529-002 EB0918529-003
Compound CAS Number
A Suspended Solids (SS) -- 5 mg/L
F=T- ..•. +
^ Total Hardness as CaCO3 - 1 mg/L.
ED093F: Dissolved Major Cations
5
8 20F: Dissolved Metals by 1CP-MS
7429-90-5 0.01
0.001
mg/L
1 0.07 0.26
<0.001
Arsenic 7440-38-2 mg/L _ 0.001 0.002
4
Cadmium 7440-43-9 0.0001 mg/L 0.0008 <0.0001 <0.0001
Chromium 7440-47-3 0.001 mg/L <0.001 0.001 <0.001
Copper 7440-50-8 0.001 mg/L 0.007 0.002 0.002
Lead 7439-92-1 0.001 mg/L <0.001 <0.001 <0.001
Nickel 7440-02-0 0.001 mg/L 0.005 0.002 <0.001
Zinc 7440-66-6 0005 mg/L. 0.095 0.081 0.010
Iron 7439-89-6 0.05 mg/L 0.07 2.33
EK0660: Ammonia as N by Discrete Analyser
7664-41-7 0.01 mg/l.
EK0570: Nitrite as N by Discrete Analyser
<0,0T
EK0680: Nitrate as N by Discrete Analyser
^ Nitrate as N 14797-55-8 0.01 mg/L 0.11
EK0680: NOX as N by Discrete Analyser
Nitrite + Nitrate as N --- 0.01 rng/L 0.11 0.12 0.10
EK061: Total Kjeldahl Nitrogen (TKN)
Total Kjeldahl Nitrogen as N ---- 01 ii q L
Total Kjeldahl Nitrogen as N -- 0.1 mg/L 2.1 0.7
EK0620: Total Nitrogen AsN By Discrete Analyset
Total Nitrogen as N
EK0670: Total Phosphorus as P by Discrete Analyser
% <0.01
Total Phosphorus as P -- 0.01 mg/L 0.60 0.38
EK0710: Reactive Phosphorus as P by discrete anayser
Reactive Phosphorus as P --- 0.01 mg/L <0.01 <0.01
EP002: Dissolved Organic Carbon (DOC)
Page 42
Page 4 of 6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-Maio-: WATER Client sample 10 GW 1 GW2 SW4
Client sampling date / time 23-NOV-2009 15:00 23-NOV-2009 15:00 23-NOV-2009 15:00
CAS Ninnn..-v LOP Unit EB0918529-001 EB0918529-002 ES0918529.003
EP068A: Organochlorine Pesticides (OC)
alpha-BHC 319-84-6 0.5 pg/L <0.5
Hexachlorobenzene (HCB) 118-74-1 0.5 pg/L <0.5
beta-BHC 319-85-7 0.5 pg/L <0.5
gamma-BHC 58-89-9 0.5 pg/L <0.5
delta-BHC 319-86-8 0.5 pg/L <0.5
Heptachlor 76-44-8 0.5 pg/L <0.5
Aldrin 309-00-2 0.5 pg/L <0.5
Heptachlor epoxide 1024-57-3 0.5 pg/L <0.5
trans-Chlordane 5103-74-2 0.5 pgiL <0.5
alpha-Endosulfan 959-98-8 0.5 pg/L <0.5
cis-Chlordane 5103-71-9 0.5 pg/L <0.5
Dieldrin 60-57-1 0.5 pg/L <0.5
4.4'-DDE 72-55-9 0.5 pg/L <0.5
Endrin 72-20-8 0.5 pg/L <0.5
beta-Endosulfan 33213-65-9 0.5 pg/L <0.5
4.4'-DDD 72-54-8 0.5 pg/L <0.5
Endrin aldehyde 7421-93-4 0.5 pg/L <0.5
Endosulfan sulfate 1031-07-8 0.5 pg/L <0.5
4.4'-DDT 50-29-3 2 Pg/L <2
Endrin ketone 53494-70-5 0.5 Ng.'L <0.5
Methoxychlor 72-43-5 2 pg/L <2
EP068B: Orpanophosphorus Pesticides (OP)
Dichlorvos 62-73-7 0.5 pg/L <0.5
Demeton-S-methyl 919-86-8 0.5 pg/L <0.5
Monocrotophos 6923-22-4 2 pg/L <2
Dimethoate 60-51.5 0.5 p9/L <0.5
Diazinon 333-41-5 0.5 pgiL <0.5
Chlorpyrifos-methyl 5598-13-0 0.5 pg/L <0.5
Parathion-methyl 298-00-0 2 pg/L <2
Malathion 121-75-5 0.5 pg/L <0.5
Fenthion 55-38-9 0.5 pg/L <0.5
Chlorpyrifos 2921-88-2 0.5 pg/L <0.5
Parathion 56-38-2 2 pgJL <2
Pirimphos-ethyl 23505-41-1 0.5 pgiL <0.5
Chlorfenvinphos 470-90-6 0.5 pg/L <0.5
Bromophos-ethyl 4824-78-6 0.5 pg/L <0.5
Fenamiphos 22224-92-6 0.5 pg/L <0.5
Prothiofos 34643-46-4 0.5 pg/L <0.5
- - - - - - - - - - - - - - - - - - - - -
[OCR of page images]
Page 4o0f6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0S23
Analytical Results
Sub-Matnx: WATER
Compound
alpha-BHC
Hexachlorobenzene (HCB)
beta-BHC
gamma-BHC
delta-BHC
Heptachior
Aldrin
Heptachlor epoxide
trans-Chliordane
alpha-Endosulfan
cis-Chiordane
Dieldrin
4.4°-DDE
Endrin
beta-Endosulfan
4.4-DDD
Endrin aldehyde
Endosulfan sulfate
4.4-DDT
Endrin ketone
Methoxychlior
EPO68B: Organophosphorus Pesticides (OP)
Dichlorvos
Demeton-S-methyl
Monocrotophos
Dimethoate
Diazinon
Chiorpyrifos-methy!
Parathion-methy!
Malathion
Fenthion
Chlorpyrifos
Parathion
Pirimphos-ethyl
Chiorfenvinphos
Bromophos-ethy!
Fenamiphos
Prothiofos
ae LT Oli let lain as-is (OL ed |
Client sampie [D
Client sampling date / time
CAS Number
319-84-6
118-74-1
319-85-7
58-89-9
319-86-8
76-44-8
309-00-2
1024-57-3
5103-74-2
959-98-8
5103-71-9
60-57-1
72-55-9
72-20-8
33213-65-9
72-54-8
7421-93-4
1031-07-8
50-29-3
53494-70-5
72-43-5
62-73-7
919-86-8
6923-22-4
60-51-5
333-41-5
5598-13-0
298-00-0
121-75-5
55-38-9
2921-88-2
56-38-2
23505-41-1
470-90-6
4824-78-6
22224-92-6
34643-46-4
LOR
0.5
0.5
2
0.5
0.5
0.5
2
0.5
0.5
0.5
2
0.5
0.5
0.5
0.5
0.5
Unit
pg/L
pg/L
yo/L
g/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
ug/L
pg/L
pg/L
pg/L
g/L
pg/L
ug/L
pg/L
pg/L
pg/L
g/L
pg/L
pg/L
pg/L
ug/L
ug/L
pg/L
pg/L
pg/L
g/L
pg/L
ug/L
pg/L
pg/L
g/L
pg/L
GW 1
23-NOV-2009 15:00
EB0918529-001
GW 2
23-NOV-2009 15:00
SW 4
23-NOV-2009 15:00
EB0918529-003
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<05
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<2
<0.5
<2
<0.5
<0.5
<2
<0.5
<0.5
<0.5
<2
<0.5
<05
<05
<2
<0.5
<0.5
<0.5
<0.5
<0.5
A Campbdel Brothers Linvted Compan,
j
Page 43
Page 5 of 6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-Matnx: WATER Client sample l0 GW1 GW2 SW4
Client sampling date /time 23-NOV-2009 1500 23-NOV-2009 15:00 23-NOV-2009 15:00
LOR Unit EB0918529-001 ES0918529-002 E80918629-003
Comrwun CAS Number
EP068B: Organophosphorus Pesticides (OP) -Continued
Ethion 563-12-2 0.5 pg/L <0.5
Carbophenothion 786-19.6 0.5 pg/L <0.5
Azlnphos Methyl -_- 0.5 pg/L <0.5
EP071=0: Total Petroleum Hydrocarbons
C6 - C9 Fraction 20 pg/L <20 <20
C10 - C14 Fraction 50 pg/L <50 <50
C16 - C28 Fraction 100 Ng/L <100 160
C29 - C36 Fraction 50 pg/L <50 50
EP0801071: Total Petroleum Hydrocarbons
A C10 - C36 Fraction (sum) 50 pg/L <50
=
727, 717 17
21655-73-2 0.1 % 93.0
EP068T: Organophosphorus Pesticide Surrogate
78-48-8 0.1 %
EPO8OS: TPH(VyBTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 0.1 % 113 95.6
Toluene-D8 2037-26-5 0.1 % 103 109
4-Bromofluorobenzene 460-00-4 0.1 % 102 95.5
A Car.,pr .' Brothe,s Lrrnted Cc.apa,r,
[OCR of page images]
Page 5 of 6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DEOS23
Analytical Results
Sub-Matnx: WATER Client sample ID | _ GW 4 T - Gw 2 . sw 4 waite ---
E Client sampling date / time | 23-NOV-2009 15:00 | 23-NOV-2009 15:00 | 23-NOV-2009 15:00 | — =
ey
EPO68B: Organophosphorus Pesticides (OP) - Continued
a
Ethion 563-12-2 05 yo/L ) | <0.5 | — -—
Carbophenothion 786-196 05 ug/L = I | <05 | sas =
Azinphos Methyl! | <0.5 — -—
EP07 1/080: Total Petroleum Hydrocarbons = Se
C6 - C9 Fraction —| 2 ug/L <20 | one | <20 | — -—
~C10-C14 Fraction cove 50 ug/L | <50 | anéis | <50 i ee a
C15 - C28 Fraction —| 100 | wot | <100 — 160 | --
C29 - C36 Fraction | | «50 — | —
EP080/071: Total Petroleum Hydrocarbons aaa ;
“ C10 - C36 Fraction (sum) 210 — —-
EPO68S: Organochiorine Pesticide Surrogate = Fe> Pe *
Dibromo-DDE 21655-73-2, 0.1 % see dass | 93.0 ws ee
109 — _
Said A Bit atte ee eee
1.2-Dichloroethane-D4 17060-07-0 95.5 — --
Toluene-D8 2037-26-5 | | oe — | =
4-Bromofluorobenzene 460-00-4 0.1 % i 102 | _— 968 | = | =
A Campbell Brothers Limited Company
ce ..___ eee
Page 44
Page 6 of 6
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Prop-,, DE 0923 ALS
Surrogate Control Limits
b-Maas WATER Recovery Limits (%j
CAS Number Low High
EPO68S: Organooh orInePe (ide Suflo
Dibromo-DDE 21655-73-2 10 136
EPO68T:Orpanophosphorus Pe*Hafde
78-48-8 10 110
EP08OS: TPH(VYBTEX Surma is
1.2-Dichloroethane-04 17060-07-0 80 120
Toluene-08 2037-26-5 88 110
4-Bromofluorobenzene 460-00-4 86 115
Page 45
ALS Laboratory Group
!,%AI1'IIL.AL CHEtlI-,TRY F, ILSIING SERVII:ES
Environmental Division ALS
CERTIFICATE OF ANALYSIS
Client: DUKE ENVIRONMENTAL ALS Work Order: EB0918529
Address: PO BOX 78
Laboratory: ALS Environmental
WURTULLA, OLD, 4575 Sydney
Date Sampled: 23.11.2009
Attention: JULIE SCHUBERT Date Received: 24.11.2009
Date Analysed: 30 11.2009
Quote: BN/31709 Sample Type: AQUEOUS
Project: [)E0923 No. of Samples: 1
ANALYSIS REPORT PHYTOPLANKTON IDENTIFICATION & ENUMERATION
Comments:
- Under microscopic observation, the samples were clear for algal analysis.
NOTES
7 ' ?, Itt/
Samples were preserved with Lugols Iodine solution
Duyen Nguyen
Samples were analysed in accordance with ALS Quality
Work Instruction OWI-MIC/MW024
Senior Microbiologist
(Signatory)
Results apply to sample(s) as submitted.
PTP = Potential Toxin Producers
<1 or ND = Not Detected
Organisms are reported and counted only when detected in Date Reported: 02.12.2009
the portion of 1 mL sample.
AL S Laboratory Group
r1 u1.'^:m•' .",-,wit
NATA Ac:v^ra-^ rrtn NATA S
NN<LlraA 1 ►?/8^r1N
AAA IRAI IAN LA10RATOq Iv St RNI:I s ^ rr I TO MIN 81 MKI VM CVV
••.M V406r. A-I 5-4W- NSW: I61
V loth B. iw YYrw^F Pti BG NSW 1861
P.M •61 ]e;640550F8. .F17+1;64B!00
1 of 3
Page 46
ALS Laboratory Group
ANALYTICAL CHEMISTRY 8 TESTING SERVICES
ALS
Environmental Division
ALS Sample ID: EB0918529-01
Client Sample ID: SW4
Sample Date: 23.11.2009
Sample Time: 16:30
Units: Cells/mL
CYANOPHYTES (Blue-green algae)
Chroococcales
A hanoca sa s pp. 240
Synechococcus spp. 280
Total Chroococcales 520
Nostocales
Total Nostocales <1
Oscillatoriales
Planktolyngbya minor 3600
Planktol n b a limnectica 800
Pseudanabaena spp 2500
Total Oscillatoriales 6900
Stigonematales
Total Stigonematales <1
CHLOROPHYTES (Green algae)
Chlorococcales
Monoraphidium sp 140
Pediastrum s p. 80
Scenedesmus s . 80
Selenastrum s p. 20
Zygnematales
Cosmarium sp. 20
Volvocales
Chlamydomonas sp. 20
Total Chloro h tes 360
FLAGELLATES
Eu lenoph tes
Trachelomonas sp. 100
C toph es
Cryrtomonas cp_ ,in
Total flag cllatas 240
ALS Laboratory Group
AISTRA1 IAN L.VBINAI.)Nly SFNIk (S f'f' LID ABN +4 OC9 )MOM
NATA .nasre ...- NATAS :)-I V^Oq RwW Y,AI'wS NSW:"
LOplO N.u' -n \M5.!•' P A UCC NSW '01
2 of 3
Page 47
ALS Laboratory Group
kLYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division ALS
ALS Sample ID: EB0918529-01
Client Sample ID: SW4
Sample Date: 23.11.2009
Sample Time: 16:30
Units: Cells/mL
CHRYSOPHYTES (Golden algae)
Ch so h ceae
Mallomonas sp 20
Total Chr so h tes 20
1 BACILLARIOPHYTES (Diatoms)
Centrics
Melosira s p. 40
Urosolenia s p. 20
Pennates
Eunotia s p. 10
Gom honema s p. 30
Navicula s p. 20
Nitzschia sp 60
Pmnularia sp. 80
Total Bacillario h tes 260
TOTAL ALGAE 8300
I
ALS Laboratory Group
In. ac::.x+ n •b SJ AUSIRALIAN 7tABORAIORIV SERVKES PTV LIU ABN 641 )36009
NATA accana.[^.l' VAIAs $01 VAOeorw ROta S-W w NSW:I6
we wsw Nu>w•N'IM19
V tom" N9 105 Wselr.l Pr. BC NSW 1651
--._._...^_
3 of 3
Page 48
Scientific Analytical Services
/ 8N 72 002 765 795
Biological Accreditation Number 11085
Chemical Accreditation Number 11750
CITY BUSINESS
180 Ashridge Road
Derra Brisbane QId 4076
Dedicated to a better Brisbane
Telephone 07 3407 2666
Facsimile 07 3407 2690
Microbiology Unit Report
A unit of Brisbane City Council
Client: Duke Environmental
PO Box 78
Wurtulla
OLD 4575
Attention: Julie Schubert
Job Name: Noosa Civic DE0923
Sampling Date: 26/11/2009
Sampled By: Client
Sampling Method: Grab
Sample Matrix: Aqueous
Batch Number: 09/14410
Registration Date: 26/11/09
Analysis Date and Time: 26/11/2009 at 16:20
Date of Report: 1/12/09
Test Description Units Method 09/14410/1 09/14410/2
GW1 GW2
Time of Sampling hrs 0626 0639
Faecal Coliforms cfu/100mL 4.404 <10 <10
(MF)
B Phillips NATA
Supervising Microbiologist
TECHNICAL
COMPETENCE
ThK OV: ^.^e•a ,.,e0In
INnT11'1
iCC lefll3lt C'" le^11"W161f&
'Please note that the above results refer only to the samples tested, Page 1 of 1
and not to the batches from which they were drawn.
I
Page 49
RCU15. (u(, .
CHAIN OF CUSTODY DOCUMENTATION
CLIENT: Duke Environmental SAMPLER: SH
AL5
ADDRESS I OFFICE: PO Box 78. Wurtulla QLD 4575 MOBILE: 0418 797 956
ALS Laboratory Group
PROJECT MANAGER (PM):JUlit3 Schubert PHONE: 07 5493 3322
PROJECT ID: DE0923 EMAIL REPORT TO: &Mdukenviro-com.au
SITE: Noosa Civic P.O. No.: 291821 EMAIL INVOICE TO: (it dterant to report)
RESULTS RECUIRLD (Date): QUOTE NO.: BN/423/08 ANALYSIS REQUIRED including SUITES (note - suite codes must be listed to attract suite prices)
F LABORATORY USE ONCY / ECIAL HANDLING !STORAGE DISPOSA rg Notes e.g. Highly contaminated samples
2 w
t rn e
6 0 64 R ' m $ 06 O 9-g. "High PAHs a acted'.
Inl Yes tvo WA ; -' n . 2 0 $ a Ezra volume for QC or trace LORs etc.
SAhP ETEMPERA7l,JRE e a Iq > = c
a m B c m m
.,No? I },,
CHIL ED Ye o ° L) 8
5f1MPLE INFORMA710N {not S = Soil, W=W CONT iNER IN MATZO fl.
e N
c
ALS ID SAMPLE ID MATRIX DATE Y
Trne Type /Code Total bottles in r'n w w co
w w 3 O O r
Gix 1 w 23!11/2009 7 Coliforms nearing hotdtrtg time
Gw 2 w 23/11/2009 3
SW 4 w 23111/2009 10
Environmental Division
Brisbane
T Work Order
EB0918529
Telephone : +61-7-324372;-2
RELINQ UISHED BY: _ REC EIVED BY M M OD OF SHI EMgK
Name: Stephen Hayes Date: tt 0-1 Name: ' Date _2 `n / 0' Con' Note No:
Of. Duke Environmental Time: p Of: S C Time: rS C^
Name: Date: Name: Date: Transport Co:
Of: Time: Of: Time: Couriers Please
Water Container Codes: P = Unpreserved Plastic N = Nitric Preserved Plastic: ORC = Nitric Preserved ORC: SH = Sodium Hydroxid&Cd Preserved; S = Sodtum Hydroxide Preserved Plastic; AG = Amber Glass Unpreserved;
V - VGA Vial HCI Preserved; VS = VOA Vial Sulphuric Preserved: SG = Sulfuric Preserved AmberGlass. H - HCI preserved Plastic; HS = HC: preserved Speciation bottle; SP = Suduric Preserved Plastic F = Formekieltyde Preserved Glass;
Z = Zinc Acetate Preserved Bottle; E = EDTA Preserved Bottles: ST = Sterile Bottle; ASS = Plastic Bag for Acid Sulphate Silts; B - Unpreserved Bag.
ALS LABORATORY GROUP COC Page _L of 1
Page 50
ALS Laboratory Group
ANALYTICAL CHEMISTRY 9 TESTING SERVICES
Environmental Division ALS
SAMPLE RECEIPT NOTIFICATION (SRN)
Comprehensive Report
Work Order EB0918529
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
1 Contact
Address
MS JULIE SCHUBERT
PO BOX 78
WURTULLA QLD, AUSTRALIA 4575
Contact
Address
Tim Kilmister
32 Shand Street Stafford QLD Australia
4053
E-mail [email protected] E-mail [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 Page 1 of 2
Order numbs 291821
C-C-C number Quote number EB2009DUKENVO216 (BN131709)
Site Noosa Civic
Sampler SH QC Level NEPM 1999 Schedule B(3) and ALS
QCS3 requirement
Dates
Date Samples Received 24-NOV-2009 Issue Date 25-NOV-2009 13 44
Client Requested Due Date 02-DEC-2009 Scheduled Reporting Date
02-DEC-2009
Delivery Details
Mode of Delivery Carrier Temperature 5.2°C - Ice bricks present
No of coolers/boxes 1 MEDIUM No of samples received 3
Sercunty Seal Intact. No of samples analysed 3
General Comments
• This report contains the following information:
Sample Container(s)/Preservation Non-Compliances
1 •
Summary of Sample(s) and Requested Analysis
Requested Deliverables
Samples received in appropriately pretreated and preserved containers.
• Sample(s) requiring volatile organic compound analysis received in airtight containers (ZHE).
• Breaches in recommended extraction / analysis holding times may occur.
• Microbiological testing will be subcontracted to Brisbane City Council Laboratory.
• Please be advised that samples were received after 03:00pm on 24/11/09 and BCC
last minute pick up time. Beyond the 3:00pm cut off time that marks of the next day
pick up time that makes the microbiological analysis breaching the 24 hours from the time of
sampling.
• The recommended holding time for microbiological analysis is 24 hours from the time of
sampling.
• Please direct any turn around / technical queries to the laboratory contact designated above,
t •
•
•
Please direct any queries related to sample condition / numbering / breakages to Maggie Kahi
Analytical work for this work order will be conducted at ALS Brisbane
Sample Disposal - Aqueous (14 days), Solid (90 days) from date of completion of work order.
Enulronmental Orulslon Brisbane
ca-rALS Laboretorq Group
1 Tel. +61 -i 3243 222 F I -^ 1 r rrlrrli^rr^'om
1
Page 51
Issue Date 25-NOV-2009 13 44
Page 2 of 2
Won O' E00918529
Client DUKE ENVIRONMENTAL ALS
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA. USEPA standards.
• No sample container/ preservation non-compliance exist.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process neccessary for the execution of client requested
tasks Packages may contain additional analyses, such as
the determination of moisture content and preparation
tasks, that are included in the package.
6
When date(s) and/or time(s) are shown bracketed. these
z
have been assumed by the laboratory for processing
purposes. If the sampling time is displayed as 0:00 the _
U) 0 y o r
information was not provided by client.
O L O
Q d tu YO
WATER W W
wa
Laboratory sample Client sampling Client sample ID - mWa ,,
V
ID date / brae 0 C FI
EB0918529-001 23-NOV-2009 15 00 GW 1 3
^EB0918529-002 23-NOV-2009 15 00 GW2 3 3 3
EB0918529-003 23-NOV-2009 1500 SW4 3 3
i
b x
2 z
r
0z
in r
a F O
N
Matnr: WATER OC I- a
2F ?
2 a
Client sample ID W z a ir IX
Laboratory sample Ci,enr sarnpn„g i,
ID date, bare S 1g
% w a
EB0918529.001 23-NOV-2009 15.00 GW 1 3 3 3 3
EB0918529-002 23-NOV-2009 1500 GW 2 3 3
EB0918529-003 23-NOV-2009 1500 SW4 3 3 3 3
Pequest e r! De l i v -v: b/es
MS JULIE SCHUBERT
'AU Certificate of Analysis - NATA ( COA ) Email julie®dukenviro.com.au
'AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI ) Email julie©dukenviro.com.au
`AU QC Report - DEFAULT (Anon OC Rep) - NATA (QC ) Email [email protected]
A4 - AU Sample Receipt Notification - Environmental ( SRN ) Email Julie©dukenviro.com.au
A4 - AU Tax Invoice ( INV) Email [email protected]
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Page 52
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division ALS
QUALITY CONTROL REPORT
EB0918529 Page 1 of 8
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia 4053
WURTULLA QLD, AUSTRALIA 4575
E-mail [email protected] E-mail [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 QC Level NEPM 1999 Schedule B(3) and ALS QCS3 requiremer
Site Noosa Civic
C-O-C number Date Samples Received 24-NOV-2009
Sampler SH Issue Date 02-DEC-2009
Order number 291821
No. of samples received 3
Quote number BN/317/09 No. of samples analysed 3
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for
release.
This Quality Control Report contains the following information:
• Laboratory Duplicate (DUP) Report: Relative Percentage Difference (RPD) and Acceptance Limits
• Method Blank (MB) and Laboratory Control Spike (LCS) Report; Recovery and Acceptance Lints
• Matrix Spike (MS) Report; Recovery and Acceptance Lints
NATA Accredited Laboratory 825 Signatories
This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been
NATA This document is issued in
accordance with NATA
carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Position Accreditation Category
accreditation requirements.
Kim McCabe Senior Inorganic Chemist Inorganics
Sarah Ashworth Organic Chemist Organics
Aceredil ,d for compliance with
ACCREDITATION ISO IEC 17025.
Enulronmental Diulsion Brisbane
Pail of the ALS Laboratory Group
33 Snand Street Slafrord OLD A-1ralia 4052
Ter, +817.3243 7222 Fe
Page 53
Page 2of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923
General Comments
The on,dyl cal procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Key Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot
CAS Number - CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed OC
- - - - - - - - - - - - - - - - - - - -
Page 54
Page 3 of 8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Laboratory Duplicate (DUP) Report
The qualdv control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges
for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method OW-EN/38and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:-
No Licit; Result between 10 and 20 times LORI- 0% - 50%; Result > 20 times LORI- 0% - 20%.
Sub-Matrrr: WATER Laboratory Duplicate (DUP) Report
Laboratory sample ID Client s.mp/e i0 CA$Number l LOR -Unit Original Result Duplicate Result RPD (%) Recovery Limits (°e)
EA025: Suspandsd Solids (QC Lot: 1176457)
E60918500.001 Anonymous EA025H: Suspended Solids (SS) mg/L 7 8 13.3 No Limit
EB0918726-003 Anonymous EA025H: Suspended Solids (SS) mg/L. 166 170 2.4 0%-20%
ED085F: Dissolved Major Cations (QC Lot: 1174888)
EB0918510-002 Anonymous ED093F: Calcium 7440-70-2 mg/L 56 58 2.6 0%-20%
ED093F: Magnesium 7439-95.4 mg/L 19 19 0.0 0%-50%
E60918563-004 Anonymous ED093F: Calcium 7440-70-2 mg/L 14 14 0.0 0%-50%
ED093F: Magnesium 7439-95-4 mg/L 28 28 0.0 0%-20%
EO020F: Dissolved Metals by ICP.MS (QC Lot: 1174616)
EB0918472-005 Anonymous EG020A-F Cadmium 7440-43-9 0.0001 mg/L 0.0001 0.0001 0.0 No Limit
EG020A-F Arsenic 7440-38-2 0.001 mg/L 0.002 0.002 0.0 No Limit
EG020A-F Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.004 0.004 0.0 No Limit
EG020A-F: Lead 7439-92.1 0.001 mg/l. <0.001 <0.001 0.0 No Limit
EG020A-F: Nickel 7440-02.0 0.001 mg/L 0.003 0.003 0.0 No Lime
EGO20A-F: Zinc 7440.1%41 0.006 mg/L 0.038 0.038 0.0 No Lune
EG020A-F: Aluminium 7429-905 0.01 mg/L 0.01 0.01 0.0 No Limit
EG020A-F: Iron 7439-89.61 0.05 mg/L 0.20 0.20 0.0 No Limit
EB0918539-003 Anonymous EG020A-F: Cadmium 7440-43-9 0.0001 mg/L 0.0006 0.0006 0.0 No Limit
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.003 0.003 0.0 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L 0.001 0.002 0.0 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L 0.002 0.002 0.0 No Limit
EG020A-F Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F. Nickel 7440-02-00 001 mg/L 0-002 0002 0.0 No Lime
EG020A-F: Zinc 7440-6-6 0.005 mg/L 0.006 0.008 15.1 No Lime
EG020A-F Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.0 No Lime
EG02OA-F Iron 7439-89-6 0.05 mg/L 2440 2560 4.6 0%-20%
EO020F: Dissolved Metals by ICP-MS (QC Lot 117462111)
EB0918512-065 Anonymous EG020A-F: Cadmium 744043-9: 00001 mg/L. <0.0001 <0.0001 0.0 No Limit
EG020A-F: Arsenic 7440-38-21 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Chromium 744047-3: 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Copper 7440-50-8- 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Nickel 7440-02-01 0.001 mg/L <0.001 <0.001 0.0 No Lmt
EG02OA-F Zinc 7440-6- 0.005 mg/l. <0 005 <0.005 0.0 No Lad
EG020A-F. Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.0 No Limit
4 Campt& B'olhe Lvrried (:arrparn
Page 55
Page 4of8
Work Ordei EB0918529
Client DUKE ENVIRONMENTAL
Prole. i DE0923
WATER Laboratory Ducllcale iPUP) Report
iJGOre^r,,, rnrpie ID Cl,enr sample ID
Original Resulr Duplicate Result RPD (Saf Recovery Limits i"a l
c'i r n' w
EB0918512-065 Anonymous EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 <0.05 0.0 No Limit
EB0918515-003 Anonymous EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 <0.0001 0.0 No Limit
EG020A-F: Arsenic 7440-38-2 0.001 mg/L 0.007 0.007 0.0 No Limit
EG020A-F: Chromium 7440-47-3 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 <0.001 00 No Limit
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Nickel 7440-02-0 0.001 mg/L <0.001 <0.001 0.0 No Limit
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 <0.005 0.0 No Limit
EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.05 0.05 0.0 No Limit
EG020A-F. Iron 7439.89-6, 0.05 mg/L 0.07 0.06 0.0 No Limit
EKO550: Ammonia as N by Discrete Analyser (QC Lot: 1178888)
E60918529-001 GW 1 EK055G Ammonia as N 7664-41-7 0.01 mg/L 0 28 0.27 00 0%-20%
EK0570: Nitrite as N by Discrete Analyser (QC Lot: 1174185)
EB0918448-001 Anonymous EK057G: Nitrite as N 0.01 mg/L 0.07 0.07 oC No Lin
EB0918510.002 Anonymous EK057G Nitntrl as N 0.01 mg/L 0.01 0.01 oc NoLimr
EK0590: NOX as N by Discrete Analyser (QC Lot: 1178854)
EB0918471-004 Anonymous EK059G Nitrite + Nitrate as N 0.01 mg/L 0.07 0.06 00 No Limit
E80918529-001 GW1 EK059G: Nitrite + Nitrate as N 0.01 mg/L 0.11 0 10 00 0% - 50%
EK061: Total Kjeldahl Nitrogen (TKN) (QC Lot: 1175186)
EBO918467-002 Anonymous EK061G. Total Kjeldahl Nitrogen as N 0.1 mg/L 2.7 26 0.0 0% - 20
EB0918529-001 GW 1 EK061G. Total Kjeldahl Nitrogen as N mg/L 2.1 2 0 7.8 0%-20 11
EKO67C Total Phosphorus as P by Discrete Analyser (QC Lot: 1178187)
EB0918467-002 Anonymous EK067G: Total Phosphorus as P 0.01
a^
mg/L 4.84 5.00 32 0%-20%
EB0918540-003 Anonymous EK067G: Total Phosphorus as P 0.01 mg/L 0.04 0.05 25 8 No Limit
EK0710: Reactive Phosphorus as P by discrete anatyser (QC Lot: 1174686)
EB0918448-001 Anonymous EK071G: Reactive Phosphorus as P 0.01 mg/L 7.40 7.31 12 0%-20%
EB0918323-003 Anonymous EK071G: Reactive Phosphorus as P 0.01 mg/L <0.01 <0.01 00 No Limit
EP002: Dissolved Orgarnic Carbon (DOC) (QC Lot: 1177018) I.
EB0918529-003 SW4 EP002: Dissolved Organic Carbon mg/L 14 14 00 0%-50%
EB0918674-007 Anonymous EP002: Dissolved Organic Carbon mg/L 5 4 00 No Limit
EP080/071: Total Petroleum Hydrocarbons (QC Lot: 1178331)
EB0918483.001 Anonymous EP080 C6-C9 Fraction 20 pg/L <20 <20 00 No Limit
E60918540-006 Anonymous EPO80: C6 - C9 Fraction 20 pg!L <20 <20 0a No Limit
Page 56
Page 5 of 8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Protect DE0923 ALS
Method Blank (MB) and Laboratory Control Spike (LCS) Report
The quality control term Method Laboratory Blank refers to an anatvte free matrix to vihich all reagents are added in the same volumes or proportions as used in standard sample preparation The purpose of lhns CC
parameter is to monitor potential laboratory contamination The quality control term Laboratory Control Sample (LCS) refers to a certified reference rrmterial, or a known interference free matrix spiked with target
analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.
Sub-Matrix: WATER Method Blank (MB) Laboratory Control Spike (LCS) Report
Report Spike Spike Recovery (%) Recovery Limits (%)
I
Method: Compound Numb
CAS LOR Unit Result Concentration LCS I Low High
EA025: Suspended Solids (QCLOt: 1179437)
EA025H: Suspended Solids (SS) mg/L <5 j 150 mg/L 107 86 108
ED093F: Dissolved Major Catlons(QCLat:_ 1174688)
EG02OF: Dissolved Metals by ICP-MS (QCLot:1174815)
EG020A-F: Aluminium 7429-90-5 0.01 ng/L <0.01 0.500 mg/L 101 76 130
EG020A-F: Arsenic 7440-38-2 0.001 mg/L <0.001 0.100 mg/L 98.2 80 124
EG020A-F: Cadmium 7440-43-9 0.0001 mg/L <0.0001 0.100 mg/L 106 89 117
EG02OA-F: Chromium 7440.47-3 0.001 mg/L <0.001 0.100 mg/L 106 85 127
EG020A-F: Copper 7440-50-8 0.001 mg/L <0.001 0.200 mg/L 95.8 85 119
EG020A-F: Lead 7439-92-1 0.001 mg/L <0.001 0.100 mg/L 106 88 116
EG020A-F: Nickel 7440-02-0 0001 mg/L <0.001 0.100 mg/L 96.8 85 119
EG020A-F: Zinc 7440-66-6 0.005 mg/L <0.005 0.200 mg/L 103 86 130
EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 0.50 mg/L 104 79 128
EG02OF: Dissolved Metals by ICP-MS (QCLot:1174628)
EG020A-F: Aluminium 7429-90-5 0.500 mg/L 90.9 76 130
EG020A-F: Arsenic 7440-38-2 0.100 mg/L 99.2 80 124
EG02OA-F: Cadmium 7440-43-9 0.100 mg/L 103 89 117
EG020A-F: Chromium 7440-47-3 0.100 mg/L 106 85 127
EG020A-F: Copper 7440-50-8 0.200 mg/L 103 85 119
EG020A-F: Lead 7439-92-1 0.100 mg/L 98.9 88 116
EG02OA-F: Nickel 7440-02-0 0,100 mg/L 105 85 119
EG02OA-F: Zinc 7440-66-6 0.200 mg/L 100 86 130
EG02OA-F: Iron 7439-89-6 0.50 mg/L 106 79 128
EK086O: Ammonia as N by Discrete Analyser (QCLot:1178355)
EKO55G,Ammon aasN 7664-41-7 0 01 mg/L 129
EK0670: Nitrite as N by Discrete Analyser (QCLot:1174886)
EK057G 0 01 103 74 128
T
EK0690: NOX as N by Discrete Analyser (QCLot:1176354)
EK059G Nitrite + Nitrate as N 90.4 70 130
EK061: Total Kjeldahl Nitrogen (TKN) (QCLot:1175188)
EK061G: Total Kjeldahl Nitrogen as N 0 1 <0.1 85.8 70 115
iEK067O: Total Phosphorus as P by Discrete Analyser (QCLCt: 1176187)
Page 57
rage 6of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Sub-M itr =: WATER Method Blank (MB) Laboratory Control Spike (LCS) Report
Report Spike Spike Recovery (%) Recovery Limrt$ (%)
LCS LOW High
EK087G: Total Phosphorus as P by Discrete Analysar (QCLot:_ 1178187) * ctnt)nwd
EK067G: Total Phosphorus as P 0.01 mg/L <0.01 4.2 mg/L 98.3 117
EK0710: Reactive Phosphorus as P by discrete analyser (QCLOtz 1174888)
EK071G: Reactive Phosphorus as P 0.01 rrg/L <0.01 y 0 5 mg/L 103 71 129
.t
EP002: Dissolved Organic Carbon (DOC) (QCLot: 1177018)
EP002: Dissolved Organic Carbon mg/L <1 100 mg/L 85,3 sa 116
EP088A: Organochlorine Pesticides (OC) (QCL0t;1174482
EP068: alpha-BHC 319-84-6 0.5 pg/L <0.5 5 pg/L 80.7 55 125
EP068: -texachlorobenzene (HCB) 118-74-1 0.5 pg/L <0.5 5 pg/L 72.4 51 121
EP068 beta-BHC 319-85-7 0.5 pg/L <0.5 5 pg/L 78.7 54 126
EP068: gamma-BHC 58-89-9 0.5 pg/L <0.5 5 pg/L 81.2 53 131
EP068 delta-BI-IC 319-86-8 0.5 pg/L <0.5 5 pg/L 75.4 52 131
EP068 Heptachlor 76-44-8 0.5 P9/L <0.5 5 pg/L 69.7 43 128
EP068: Aldrin 309-00-2 0.5 p9/L <0.5 5 pg!L 75.1 57 126
EP068: Heptachlor epoxide 1024-57-3 0.5 pg/L <0.5 5 pg/L 76.3 57 124
EP068: trans-Chlordane 5103-74-2 0.5 pg/L <0.5 5 pg/L 73.5 53.4 120
EP068: alpha-Endosultan 959-98-8 0.5 pg/L <0.5 5 pg/L 78.7 53 131
EP068: cis-Chlordane 5103-71-9 0.5 pg/L <0.5 5 pg/L 75.6 52.4 120
EP068: Dieldrin 60-57-1 0.5 pg/L <0.5 5 pg/L 76.2 51 128
EP068 4.4 -DDE 72-55-9 0.5 pg/I <0.5 5 pg/L 74.2 54.8 125
EP068:Endnn 72-20-8 0.5 pg/I <0.5 5 pg/L 76.1 49.1 135
EP068:beta-Endosulfan 33213-65-9 0.5 p9/L <0.5 5 pg/L 79.9 54 123
EP068: 4.4'-DDD 72-54-8 0.5 pg/I <0.5 5 pg/L 79.6 54.3 129
EP068: Endrin aldehyde 7421-93-4 0.5 p9/L <0.5 5 pg/L 94.8 54.3 127
EP068 Endosulfan sulfate 1031-07-8 0.5 pg/L <0.5 5 pg/L 66.9 47 136
EP068: 4.4'-DDT 50-29-3 2.0 pg/L <2 5 pg/L 75.3 40 130
EP068: Endrn ketone 53494-70-5 0.5 pg/L <0.5 5 pg/L 83.2 43 137
EP068: Methoxychlor 72-43-5 2.0 p9/L 5 pg/L 75.3 40 130
EP088B: Organophosphorus Pesticides (OP) (QCLot: 1174482)
EP068 Dichlorvos 62-73-7 0.5 pg/I <0.5 5 pg/L 71.9 53.6 126
EP068 Demeton-S-methyl 919-86-8 0.5 pg/I <0.5 5 pg/L 79.9 49.2 135
EP068 Monocrotophos 6923-22-4 2.0 pg/L <2 5 pg/L #9.9 17.5 100
EP068 Dimethoate 60-51-5 0.5 pg/I <0.5 5 pgiL 67.9 51.3 125
EP068 Diazinon 333-41-5 0.5 pg/L <0.5 5 pg/L 79.8 52 126
EP068 Chlorpyrifos-methyl 5598-13-0 0.5 pg/L <0.5 5 pg/L 71.9 54.6 123
EP068 Parathion-methyl 298-00-0 2.0 pg/L <2 5 pg/L 80.2 50 130
EP068 Malathion 121-75-5 0.5 pg/L <0.5 5 pg/L 76.4 51 129
EP068 Fenthion 55-38-9 0.5 pg/I <0.5 5 pg/L 74.0 54 120
EP068 Chlorpynfos 2921-88-2 0.5 pg/L <0.5 5 pg/L 77.2 57.6 122
- - - - - - - - - - - - - - - - - - - -
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Page
6of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923
ALS
Sub-Matrix: WATER
Method: Compound
EKO71G: Reactive Phosphorus as P
EP002: Dissolved Organic Carbon (DOC) (QCLot: 1177018)
EP002: Dissolved Organic Carbon
EP068A: Organochiorine Pesticides (OC) (QCLot: 1174482)
EPO68: alpha-BHC
EPO68: Hexachlorobenzene (HCB) 118-74-1
EP068: beta-BHC 319-85-7
EPO68: gamma-BHC 58-89-9 |
EPO68: delta-BHC 319-86-8
EPO68: Heptachlor 76-44-8
EPO68: Aldrin 309-00-2
EPO68: Heptachior epoxide 1024-57-3 |
EPO68: trans-Chiordane 5103-74-2
EPO68: alpha-Endosulfan 959-98-8
EP068: cis-Chlordane 5103-71-9 |
EPO68: Dieidrin 60-57-1
EP068: 4.4°-DDE 72-55-9
EP068: Endrin 72-20-8 |
EP068: beta-Endosulfan 33213-65-9 |
EP068: 4.4°-DDD 72-54-8 |
EPO68: Endrin aldehyde 7421-93-4 |
EP068: Endosulfan sulfate 1031-07-8 |
EPO68: 4.4°-DDT 50-29-3 |
EP068: Endrin ketone 53494-70-5 |
: Methoxychlor
EPO68B: Organophosphorus Pesticides (OP) (QCLot: 1174482)
CAS Number
319-84-6 |
72-43-5 |
EP068: Dichlorvos 62-73-7
EP068: Demeton-S-methy! 919-86-8
EP068: Monocrotophos 6923-22-4
EPO68: Dimethoate 60-51-5
EP068; Diazinon 333-41-5 |
EP068: Chlorpyrifos-methy! 5598-13-0 |
EPO68: Parathion-methy!| 298-00-0
EP068: Malathion 121-75-5 |
EP068: Fenthion 55-38-9 |
2921-88-2
EPO68: Chiorpyrifos
Method Blank (MB) Laboratory Control! Spike (LCS) Report
Report
— : Spike Spike Recovery (%) Recovery Limits (%)
LOR Unit Result Concentration Lcs Low High
4.2 mg/L 98.3 73 117
0.5 mg/L 103 71 129
he
100 mg/L 85.3 80 116
0.5 ug/L <0.5 5 pg/L 80.7 55 125
05 ug/L <0.5 5 pg/L 72.4 51 121
0.5 | pg/L <0.5 5 po/L 78,7 54 126
0.5 pg/L 05 5 pg/L 81.2 53 131
0.5 po/L <0.5 5 po/L 75.4 52 131
0.5 pg/L <0.5 5 pg/L 69.7 43 128
0.5 pg/L <0.5 5 pg/L 75.1 57 126
0.5 ug/L <0.5 5 pg/L 76.3 57 124
0.5 ug/L <0.5 5 pg/L 73.5 53.4 120
0.5 ug/L <0.5 5 o/b 78.7 53 131
0.5 ug/L <0.5 5 pg/L 75.6 52.4 120
0.5 yo/L <0.5 5 po/L 76.2 51 128
0.5 pg/L <0.5 5 pg/L 742 548 125
0.5 pg/L <0.5 5 po/L 76.1 49.1 135
0.5 | yo/L <0.5 5 pg/L 79.9 54 123
0.5 | pg/L <0.5 5 pg/L 79.6 54.3 129
0.5 | ug/L <0.5 5 po/Lb 94.8 54.3 127
0.5 ug/L | <0.5 5 pg/b 66.9 47 136
2.0 pg/L <2 5 pg/L 13.3 40 130
0.5 pg/L <0.5 5 pg/L 83.2 43 137
<2 | 5 pg/L 75.3 40 130
aes
0.5 ug/L <05 5 g/L 71.9 53.6 126
05 pg/L <0.5 5 pa/L 79.9 49.2 135
2.0 ug/L <2 5 po/L #9.9 175 100
0.5 pg/L <0.5 5 pg/L 67.9 51.3 125
0.5 pg/L <0.5 5 pg/L 79.8 52 126
0.5 pg/L <0.5 5 pg/L 71.9 54.6 123
2.0 pg/L <2 5 pg/L 80,2 50 130
0.5 ug/L <0.5 5 pg/L 76.4 51 129
0.5 po/L <0.5 5 pg/L 74.0 54 120
0.5 pa/L <05 5 po/L 77.2 57.6 122
4 “srpiheal! F tiuere | ore vT
. . PTH . " . t CVIIDS Ty
Page 58
Page 7 of 8
Work Order E80918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Sub-Matrix: WATER Method Blank (MB)
Report Spike Spike Recovery (%) Recovery Limits (%)
Concentration LCS Low High
EP088B: Organophosphorus Pesticides (OP) (QCLot:1174482) - continued
EP068: Parathion 56-38-2 2.0 <2 5 pg/L 78.1 51.8 126
EP068: Pirimphos-ethyl 23505-41-1 0.5 <0.5 5 pg/L 67.0 54.7 122
EP068: Chlorfenvinphos 470-90-6 0.5 <0.5 5 pg/L 63.3 54.7 130
EP068: Bromophos-ethyl 4824-78-6 0.5 <0.5 5 pg/L 67.0 54.8 120
EP068: Fenamiphos 22224-92-6 0.5 <0.5 5 pg/L 77.8 48.3 126
EP068: Prothiofos 34643-46-4 0.5 <0.5 5 pg/L 74.4 53.7 121
EP068: Ethion 563-12-2 0.5 <0.5 5 pg/L 75.1 54.6 130
EP068: Carbophenothion 786-19-6 ' 0.5 <0.5 5 pg/L 75.4 53.4 128
EP068: Azinphos Methyl <0.5 5 pg/L 51.7 34 130
EP080 11: Total Petroleum Hydrocarbons (QCLot:1174480)
EP071: C10 - C14 Fraction 50 pg/L <50 1200 pg/L 124 49 125.5
EP071: Cl5 - C28 Fraction 100 pg/L <100 2040 pg/L 128 58 130
EP071 C29-C36 Fraction 50 pg/L <50 -
EPO801071: Total Petroleum Hydrocarbons (QCLct 1170331)
20 pg/L <20 160 pg/L 1 111 73 135
^ .. 1
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Page 7of8
Work Order - EBO918529
Client DUKE ENVIRONMENTAL .
Project DE0923 ALS
Sub-Matrix: WATER
Method Blank (MB)
Laboratory Control! Spike (LCS) Report
Report | Spike Spike Recovery (%) Recovery Limits (%)
Method: Compound CAS Number LOR | Unit ; Result | Concentration LCS Low High
EP068B: Organophosphorus Pesticides (OP) (QCLot: 1174482) - continued ae SF Bs baer
EPO068: Parathion 56-38-2 | 2.0 pg/L <2 / Sg/h 78.1 51.8 126
EP068: Pirimphos-ethy! 23505-41-1 | 05 ygiL <0.5 5 pg/L 67.0 54.7 122
EP068: Chlorfenvinphos 470-90-6 | 0.5 ug/L <0.5 | 5 pg/L 63.3 54.7 130
EP068: Bromophos-ethy! 4824-78-6 | 0.5 yg/L <0.5 : 5 pg/L 67.0 54.8 120
EP068: Fenamiphos 22224-92-6 05 pg/L <05 5 g/l 778 48.3 126
EP068: Prothiofos 34643-46-4 | 05 pg/L <0.5 5 g/L 74.4 53.7 121
EP068: Ethion 563-12-2 | 05 ug/L <0.5 5 pg/L 75.1 54.6 130
EP068: Carbophenothion 786-19-6 | 05 | ug/L <0.5 5 pg/L 75.4 53.4 128
EP068: Azinphos Methy! — 05 pg/L <0.5 5 pg/L 51.7 34 130
SARC tan Ticino E LCT) a
EP071: C10 - C14 Fraction — 50 ug/L <50 1200 jig/L 124 49 125.5
EPO071: C15 - C28 Fraction — 100 ug/L <100 2040 jig/L 128 58 130
EP071: C29 - C36 Fraction —_ 50 pg/L <50 — — —_ ane
EP080/071: Total Petroleum Hydrocarbons (QCLot: 1176331) e: |
EPO80: C6 - C9 Fraction on 20 ug/L <20 "460 pg/L 111 73 135
Brothers Ler
. > ’
A Campbet
Page 59
Page 8 of 8
Work Cnl i EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923
Matrix Spike (MS) Report
The quality control term Matrix Spike (MS) refers to an inlralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC pararrxaer is to monitor potential matrix effects on analyte
recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DOOs). Ideal recovery ranges stated may be waived in the event of sample matrix etertorence
Sub-Matur.: WATER Matrix Spike (MS) Report
Spike Recovery (%) Recovery Limits r%)
MS Low High
3020F: Dissolved Metals by ICP-MS (QCLot: 1174816)
EB0918484-001 Anonymous EG020A-F: Aluminium 7429-90-5 0.5 mg/L 104 70 130
EG020A-F: Arsenic 7440-38-2 0.100 mg/L 105 70 130
EG020A-F: Cadmium 7440-43-9 0.100 mg/L 119 70 130
EG020A-F: Chromium 7440-47-3 0.100 mg/L 107 70 130
EG020A-F Copper 7440-50-8 0.2 mgiL 101 70 130
EG020A-F Lead 7439-92-1 0.100 mg/L 106 70 130
EG020A-F: Nickel 7440-02-0 0100 mg/L 103 70 130
EG020A-F: Zinc 7440-66-6 0.2 mg/L 112 70 130
EO02OF: Dissolved Metals by ICP-MS (QCIo 1174628)
EB0918514-001 Anonymous EG020A-F: Aluminium 7429-90-5 0.5 mg/L 103 70 130
EG020A-F: Arsenic 7440-38-2 0.100 mg/L 95.7 70 130
EG020A-F: Cadmium 7440-43-9 0.100 mg/L 100 70 130
EG020A-F: Chromium 7440-47-3 0.100 mg/L 88.5 70 130
EG020A-F: Copper 7440-50-8 0.2 rig/L 93.2 70 130
EG020A-F: Lead 7439-92-1 0.100 mg/L 100 70 130
EG020A-F: Nickel 7440-02-0 0.100 mg/L 92.3 70 130
EG020A-F: Zinc 7440-66-6 0.2 mg/L 94.9 70 130
GW 2 EK055G: Ammonia as N 7664-41-7 0,4 mg/L I 82.0 70 130
R
EK0670: NNW-K* 7ilby Discrete Analyser (QCLot:1174085)
E809 1 85 10-002 Anonymous EK057G Nitrite as N 0.4 rrg!L 113 70 130
EK0680: NOX as N by Discrete Analyser (QCLot 1178864)
E5091852-9-00-2 GW 2 EK059G Nitrrte Nitrate as N 0.8 mg/L 81.9 70 130
EK061: Total Kjeldahl Ndrogen (TKN) (QCLot:1175186)
E IrD091 8500-001 Anonymous EK061G: Total Kjeldahl Nitrogen as N 5 mg/L 99.8 70 130
EK067G: Total Phosphorus as P by Discrete Analyser (QCL,ob 1173187)
EB0918500-001 Anonymous EK067G Phosphorus as P 1,0 mg/L # Not Determined 70 130
EK071'Ot Reactive Phosphorus as P by discrete analyser (QCLot: 1174686)
EB0918448-014 Anonymous EK071G: Reactive Phosphorus as P 2 0 mg/L 114 70 130
EPO80 O71: Total Petroleum Hydrocarbons (QCLot:1176331)
E60918484.001 Anonymous EP080: C6 - C9 Fraction 140 pg/L 92.0 70 130
- - - - - - - - - - - - - - - - - - - - -
Page 60
mm
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division
INTERPRETIVE QUALITY CONTROL REPORT
Work Order EB0918529 Page 1 of 8
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia 4053
WURTULLA QLD, AUSTRALIA 4575
E-mail [email protected] E-maii [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile : +61-7-3243 7218
Project DE0923 QC Level NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Site Noosa Civic
C-O-C number D. ii • Samples Received 24-NOV-2009
Sampler SH s>,i Date 02-DEC-2009
Order number 291821
No. of samples received . 3
Quote number BN/317/09 No. of samples analysed : 3
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted All pages of this report have been checked and approved for release.
This Interpretive Quality Control Report contains the following information:
• Analysis Holding Time Compliance
• Quality Control Parameter Frequency Compliance
• Brief Method Summaries
• Summary of Outliers
Enuironmcntal Diulslon Brisbane
Pan0'the ALS Laboratory Group
32 ShPnv:3red SIaM.crd QLE' ^^^v'Mv rr.
Page 61
rage 2 of 8
Nork Order EB0918529
:lent DUKE ENVIRONMENTAL
'roped DE0923
Analysis Holding Time Compliance
Thu follovnnq report sumrnarisr-t, extraction preparation and analysis times and compares with recommended holding limes. Dates reported represent first date of exb:rction or analysis and preclude-, !.nbsequent
dilutions and reruns. Information is also provided re the sample container (preservative) from which the analysis aliquot was taken. Elapsed period to analysis represents number of days from sampling where no
extraction I digestion is involved or period from extraction I digestion where this is present. For composite samples, sampling date is assumed to be that of the oldest sample contributing to the composite Sample date
for laboratory produced leachates is assumed as the completion date of the leaching process Outliers for holding time are based on USEPA SW 846. APHA. AS and NEPM (1999) A listing of breaches is provided in
the Summary of Outliers
Holding times for leachate methods (excluding elutriates) vary according to the analytes being determined on the resulting solution. For non -volatile analytes. the holding time compliance assessment compares the
leach date with the shortest analyte holding time for the equivalent soil method. These soil holding times are, Organics (14 days); Mercury (28 days) & other metals (180 days). A recorded breach therefore does not
guarantee a breach for all non-volatile parameters.
'v1..iln• WATER Evaluedroo - = Molding tone breach ; - = Wilhin holding time.
Arefhed , I" Sample Date
SW4 23-NOV-2009 30-NOV-2009 30-NOV-2009
Clear Plastic Bottle - Natural
SW4 23-NOV-2009 26-NOV-2009 21-DEC-2009
Clear Plastic Bottle - Nitric Acid; Filtered
GW 1 23-NO V -2009 26-NOV-2009 22.MAY-2010
Clear Plastic Bottle - Nitric Acid: Filtered
GW 2. W4 23-NO V -2009 30-NOV-2009 22-AAY-2010 3
Clear Plastic Bottle - Sulphuric Acid
GW 1, GW 2, 30-NOV-2009 21-DEC-2009
SW4
a
EK0670: Nkrke as N by DlecreW Analyrrer
riYr9i^^ i
Clear Plastic Bottle - Natural
GW 1. W4 26-NOV-2009 25-NOV-2009 X
Clear Plastic Bottle - Sulphuric Acid
GW 1 GW 2. 23-NOV•2008 - - - 30 NOV-2009 21-DEC-2009
SW 4
F. u. ,t
Clear Plastic Bottle - Sulphuric Acid
GW2 23-NOV-2009 30-NOV-2009 21-DEC-2009 3 30-NOV-2009 21-DEC-2009 3
Clear Plastic Bottle - Sulphuric Acid
GW 1, W4 23-NOV-2009 30-NOV-2009 21-DEC-2009 I 30-NOV-2009 21-DEC-2009 ,/
- - - - - - - - - - - - - - - - - - - - -
Page 62
Page 3 of 8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923
otrii: WATER Evaluation: x = Holding time breach = Within holding time
Date analysed Due fc analysts Evaluation
Clear Plastic Bottle - Sulphuric Acid
GW 1, GW 2, 23-NOV-2009 30-NOV-2009 21-DEC-2009 30-NOV-2009 21-DEC-2009 3
SW 4
•--- 26-NOV-2009 25-NOV-2009 x
23-NOV-2009 ---- 27-NOV-2009 21-DEC-2009
a . , TF
3-NOV-2009 26-NOV-2009 30-NOV-2009 3 30-NOV-2009 05-JAN-2010 3
23-NOV-2009 26-NOV-2009 30-NOV-2009 ] 3 30-NOV-2009 05-JAN-2010 3
Amber Glass Bottle - Unpreserved
GIN 1, 23-NOV-2009 26-NOV-2009 30-NOV-2009 V 27-NOV-2009 05-JAN-2010 3
Amber VOC Vial - HCI
GW1 30-NOV-2009 07-DEC-2009
Amber Glass Bottle - Unpreserved
GW 1, SW4 30-NOV-2009 3 27-NOV-2009 05-JAN-2010
Page 63
Page 4 of 8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Quality Control Parameter Frequency Compliance
The tollov.nng report summarises the Irequency of laboratory OC samples analysed within the analytical lot(s) in wduch the submitted sample(s) was(v:here) processed Actual rate should be greater than of equal to
the expected rate. A listing of breaches is provided in the Summary of Outliers
itrix. WATER Evaluation x = Quality Control frequency not within specification = Quality Control frequency within specification
Count Rate (%) Quality Control Specification
Analytical Methods MFfh(Kd QC Reaular Actual ExDected Evaruetmn
Ammonia as N by Discrete analyser EK055G 33.3 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Metals by ICP-MS - Suite A EG02OA-F 10.0 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Organic Carbon E P002 16.7 10.0 V/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Major Cations - Dissolved E D093F 16.7 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
V
Nitrite and Nitrate as N (NOx) by Discrete Analyser EK059G 13.3 10.0 ,/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Nitrite as N by Discrete Analyser EK057G 10.0 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Reactive Phosphorus as P-By Discrete Analyser EK071G 25.0 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Suspended Solids (High Level) EA025H 15.4 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Total Kjeldahl Nitrogen as N By Discrete Analyser EK061G 10.0 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Total Phosphorus as P By Discrete Analyser EK067G 10.0 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
TPH Volatiles/BTEX E P080 17 11.8 10.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Labotttity.Control Samples (LCS)
Ammonia as N by Discrete analyser EK055G 33.3 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Metals by ICP-MS - Suite A EG020A-F 5.0 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Organic Carbon E P002 8.3 6.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Nitrite and Nitrate as N (NOx) by Discrete Analyser EK059G 6.7 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Nitrite as N by Discrete Analyser EK057G 5.0 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Pesticides by GCMS E P068 50.0 6.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Reactive Phosphorus as P-By Discrete Analyser EK071G 12.5 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Suspended Solids (High Level) EA025H 7.7 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Total Kjeldahl Nitrogen as N By Discrete Analyser EKO61G 5.0 6.0 V/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Total Phosphorus as P By Discrete Analyser EK067G 6.0 5.0 ,/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
TPH - Semivolatile Fraction E P071 5.3 6.0 3 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
TPH Volatiles'BTEX E PO80 5.9 6.0 V/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
f=1 ?31
Ammonia as N by Discrete analyser E K055G 33.3 6.0 / NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Metals by ICP-MS - Suite A EG020A-F 6.0 6.0 V/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Dissolved Organic Carbon EP002 8.3 5.0 1/ NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Major Cations - Dissolved E D093F 8.3 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Nitrite and Nitrate as N (NOx) by Discrete Analyser EK059G 6.7 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Nitrite as N by Discrete Analyser EK057G 5.0 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Pesticides by GCMS E P068 50.0 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Reactive Phosphorus as P-By Discrete Analyser E K071 G 12.5 6.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Suspended Solids (High Level) EA025H 7.7 6.0 3 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Total Kjeldahl Nitrogen as N By Discrete Analyser EKO61G 5.0 5.0 3 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Page 64
Page 5of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Main.: WATER Evaluation: x = Quality Control frequency not within specification ; - = Quality Control Irequency within specification.
Count Rate (%) ( Quality Control Specification
Analytical Methods Method QC Regular ; Actual Expected Evaluatron I
Total Phosphorus as P By Discrete Analyser EK067G 1 20 5.0 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
TPH - Semivolatile Fraction EP071 1 19 6.3 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
TPH Volatiles/BTEX EP080 1 17 6.9 5.0 NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Ammonia as N by Discrete analyser EK055G 1 3 33.3 5.0 ALS QCS3 requirement
Dissolved Metals by ICP-MS - Suite A EG020A-F 2 40 6.0 5.0 ALS QCS3 requirement
Nitrite and Nitrate as N (NOx) by Discrete Analyser EK059G 15 6.7 5.0 ALS QCS3 requirement
Nitrite as N by Discrete Analyser EK057G 20 5.0 5.0 ALS QCS3 requirement
Reactive Phosphorus as P-By Discrete Analyser E K071 G 8 12.5 5.0 ALS QCS3 requirement
Total Kjeldahl Nitrogen as N By Discrete Analyser EK061G 20 5.0 5.0 ALS QCS3 requirement
Total Phosphorus as P By Discrete Analyser EK067G 20 6.0 5.0 ALS QCS3 requirement
TPH Volatiles/BTEX EP080 17 6.9 5.0 ALS QCS3 requirement
Page 65
Page 1 6of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Brief Method Summaries
The analyur.al procedure.:. used by the Enruonmentrd Division have been devek.ped from established internationally recogni ed procedures such as those pubhshod by the US EPA, APHA, AS and NEPM In house
developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the
Certificate of Analysis. Sources from which ALS methods have been developed are provided vnthin the Method Descriptions.
Suspended Solids (High Level) EA025H WATER APHA 21st ed., 2540D A gravimetric procedure employed to determine the amount of 'non-filterable' residue in a
aqueous sample. The prescribed GFC (1.2um) filter is rinsed with deionised water, oven dried and weighed
prior to analysis. A well-mixed sample is filtered through a glass fibre filter (1.2um). The residue on the filter
paper is dried at 104+/-2C . This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Hardness as CaCO3 EA065 WATER APHA 21st ed., 2340 B. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Major Cations - Dissolved E D093F WATER APHA 21st ed., 3120; USEPA SW 846 - 6010 The ICPAES technique ionises the 0.45um filtered sample atoms
emitting a characteristic spectrum. This spectrum is then compared against matrix matched standards for
quantification. This method is compliant with NEPM (1999) Schedule B(3) (Appdx 2)
Dissolved Metals by ICP-MS - Suite A EG02OA-F WATER (APHA 21st ed., 3125: USEPA SW846 - 6020, ALS QWI-EN/EG020): Samples are 0.45 um filtered prior to
analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions are
then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct mass
to charge ratios prior to their measurement by a discrete dynode ion detector.
Ammonia as N by Discrete analyser EK055G WATER APHA 21st ed., 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser. This method is
compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Nitrite as N by Discrete Analyser EK057G WATER APHA 21st ed., 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser. This method is
compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Nitrate as N by Discrete Analyser EK058G WATER APHA 21st ed., 4500-NO3- F. Nitrate is reduced to nitrite by way of a cadmium reduction column followed by
quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate
calculated as the difference between the two results. This method is compliant with NEPM (1999) Schedule B(3)
(Appdx. 2)
Nitrite and Nitrate as N (NOx) by Discrete EK059G WATER APHA 21st ed., 4500-NO3- F. Combined oxidised Nitrogen (N02+NO3) is determined by Cadmium Reduction
Analyser and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (1999) Schedule B(3) (Appdx.
2)
Total Kjeldahl Nitrogen as N By Discrete EK061G WATER APHA 21st ed., 4500-Norg D. 25mL water samples are digested using a traditional Kjeldahl digestion followed
Analyser by determination by Discrete Analyser. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Total Nitrogen as N (TKN + Nox) By EK062G WATER APHA 21st ed., 4500-Norg 14500-NO3-. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Discrete Analyser
Total Phosphorus as P By Discrete EK067G WATER APHA 21st ed., 4500-P B&F This procedure involves sulphuric acid digestion of a 100mL sample to break
Analyser phosphorus down to orthophosphate. The orthophosphate reacts with ammonium molybdate and antimony
potassium tartrate to form a complex which is then reduced and its concentration measured at 880nm using
Discrete Analyser. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
Reactive Phosphorus as P-By Discrete EK071G WATER APHA 21st ed., 4500-P F Ammonium molybdate and potassium antimony) tartrate reacts in acid medium with
Analyser othophosphate to form a heteropoly acid - phosphomolybdic acid - which is reduced to intensely coloured
molybdenum blue by ascorbic acid Quantification is by Discrete Analyser. This method is compliant with NEPM
(1999) Schedule B(3) (Appdx. 2)
Dissolved Organic Carbon E P002 WATER APHA 21st ed., 5310 B. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2)
M M M M M M M M M M - - - - - - - r
Page 66
Page 7of8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
AnelyEtcal A/effi s -• :: 1od
Pesticides by GCMS EP06E WATER USEPA SW 846 - 8270D Sample extracts are analysed by Capillary GC/MS and quantification is by comparison
against an established 5 point calibration curve. This method is compliant with NEPM (1999) Schedule B(3)
(Appdx. 2)
TPH - Semivolatile Fraction EP071 WATER USEPA SW 846 - 8015A The sample extract is analysed by Capillary GC/FID and quantification is by comparison
against an established 5 point calibration curve of n-Alkane standards. This method is compliant with NEPM
(1999) Schedule B(3) (Appdx. 2)
TPH Volatiles/BTEX EP080 WATER USEPA SW 846 - 8260B Water samples are directly purged prior to analysis by Capillary GC/MS and
quantification is by comparison against an established 5 point calibration curve. This method is compliant with
NEPM (1999) Schedule B(3) (Appdx. 2)
APHA 21st ed., 4500 Norg - D; APHA 21st ed., 4500 P - H. This method is compliant with NEPM (1999) Schedule
B(3) (Appdx. 2)
Separatory Funnel Extraction of Liquids ORG14 WATER USEPA SW 846 - 3510B 500 mL to 1 L of sample is transferred to a separatory funnel and serially extracted three
times using 60mL DCM for each extract. The resultant extracts are combined, dehydrated and concentrated for
analysis. This method is compliant with NEPM (1999) Schedule B(3) (Appdx. 2). ALS default excludes sediment
which may be resident in the container.
Page 67
Page 8 of 8
Work Order EB0918529
Client DUKE ENVIRONMENTAL
Proje';l DE0923
Summary of Outliers
Outliers : Quality Control Samples
The following report highlights outliers flagged in the Quality Control (QC) Report. Surrogate recovery limits are static and based on USEPA SW846 or ALS-QWIrENi38 (in the absence of specific USEPA limits). This
report displays QC Outliers (breaches) only.
Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes
Matrix: WATER
Ghent Sample ID Analyte
Labotlalory Control Sppt• (LCS) Recov rlss
EP068B: Organophosphorus Pesticides (OP) 1355697-020 Monocrotophos 6923-22-4 9.9 % 17.5-100% Recovery less than lower control limit
Matrix Spike (MS) Recoveries
EK067G: Total Phosphorus as P by Discrete Analyser E60918500-001 Anonymous Total Phosphorus as P Not -- MS recovery not determined,
Determined background level greater than or
equal to 4x spike level.
• For all matrices, no Method Blank value outliers occur.
• For all matrices, no Duplicate outliers occur.
Regular Sample Surrogates
• For all regular sample matrices, no surrogate recovery outliers occur.
Outliers : Analysis Holding Time Compliance
This report displays Holding Time breaches only Only the respective Extraction; Preparation and or Analysis component is/ale displayed.
Main,: WATER
Exh action / Pt epar ation Analvsie
Container! Client Sample ID(s) Date extracted Due for exit action Days Date analysed Due fm analysis Days
overdue overdue
26-NOV-2009 25-NOV-2009 I
E60710: Reactive Phosphorus as P by discruta analyser
Clear Plastic Bottle - Natural
GW 1, SW4 26-NOV-2009 25-NOV-2009
Outliers : Frequency of Quality Control Samples
Th.• r .Ii.:.rnrr report hsihIrthts, breaches in the Frequr•ncv of Quality Conlrol Sany,les
• No Quality Control Sample Frequency Outliers exist.
Page 68
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division ALS
CERTIFICATE OF ANALYSIS
:EB1000755 Page : 1 of6
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia 4053
WURTULLA OLD, AUSTRALIA 4575
E-mail [email protected] E-mail Services. [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 QC Level NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Order number 291825
C-O-C number Date Samples Received 15-JAN -20- -
Sampler SH i sin Date 28-JAN-2010
Site Noosa Civic
No. of samples received 5
Quote number BN/317/09 No of samples analysed 5
This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for
ielease
This Certificate of Analysis contains the following information:
• General Comments
• Analytical Results
• Surrogate Control Limits
NATA Accredited Laboratory 825 Signatories
This document has been electronically signed by the authorized signatories indicated below Electronic signing has been
NATA This document is issued in
accordance with NATA
carried out in compliance with procedures specified in 21 CFR Part 11.
Signatories Position Accreditation Category
accreditation requirements.
Duyen Nguyen Senior Microbiologist Microbiology
Kim McCabe Senior Inorganic Chemist Inorganics
womo nC0o0rn5Co Accredited for compliance with
SO+IEC 17025.
Sarah Ashworth Organic Chemist Organics
Enuironmental Olulslon Brisbane
Part o`the ALS Laboratory Group
32 Shard ;-! Stt"ap CLC'' e sua'ia 4O
Page 69
Page 2 016
Work On1,:r EB1000755
Client DUKE ENVIRONMENTAL
Proje, t DE0923 'ALS
General Comments
The aealvl cal procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (C) result is higher than the LOR, this may be due to primary sample exlradldgestate dilution and/or insuffient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client.
Key CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Lind of reporting
= This result is computed Porn individual analyte - utechons at or above the level of reporting
• EG02OA- F (Dissolved Metals): LOR raised for sample SW3 (EB1000755-004) due to saline sample matrix.
- - - - - - - - - - - - - - - - - - - - -
Page 70
Page : 30f6
Work Order E81000755
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-Matrix: WATER Client sample ID GW2 SW1 SW2 SW3 SW5
Client sampling date / time 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15 00 12-JAN-2010 15:00
E81000755.001 EB1000755-002 EB1000766-003 EB1000755-004 EB1000765-005
EA026: Suspended Solids
27 <5 35 69
70 4950 57
ED083F: Dissolved Major Cations
Calcium 7440-70-2 1 mg/L
Magnesium 7439-95.4 1 mg/L
E002OF: Dissolved Metals by ICP-MS
Arsenic 7440-38-2 0.001 mg/L 0.001 <0.050 0.002
Cadmium 7440-43-9 0.0001 mg/L 0.0001 '0 0001 <0.0005 0.0001
Chromium 7440-47-3 0.001 mg/L <0,001 <0.001 0.005 0.001
Copper 7440-50-8 0.001 mg/L 0.009 0.003 <0.050 0.008
Nickel 7440-02-0 0.001 mg/L 0.004 0.001 <0 050 0.001
Lead 7439-92-1 0.001 mg/L <0.001 <0.001 <0.005 <0.001
}
Zinc 7440-66-6 0.005 mg/L 0.120 I 0.044 <0.050 0.021
EKOS60: Ammonia as N by Discrete Analyser
7664-41-7 0.01 mg/L 0.12 0.09
EK0570: Nitrite as N by Discrete Analyser
0.01 ma/L ? 0.03 '0.01 <0.01
EK0680: Nitrate as N by Discrete Analyser
^ Nitrate as N 14797-55-8 0.01 0.06
EK0590: NOX as N by Discrete Analyser
Nitrite + Nitrate as N ---- 0.01 mg/L 0.06
EK0610: Total Kjeldahl Nitrogen By Discrete Analyser
Total Kjeldahl Nitrogen as N -- 0.1 mg/L 2.8
EK062: Total Nitrogen as N (TKN + NOx)
^ Total Nitrogen as N -- 0.1 mg/L 2.9
EKO670: Total Phosphorus as P by Discrete Analyser
Total Phosphorus as P --- 0.01 mg/L
EK0710: Reactive Phosphorus as P by discrete analyser
Reactive Phosphorus as P ... 0.01 mg/L <0.01 <0.01
EP002: Dissolved Organic Carbon (DOC)
Dissolved Organic Carbon -- 1 mg/L
EPOe8A: Organochlorlne Pesticides (OC)
alpha-BHC 319-84-6 0.5 pg/L -- <0.5 <0.5 <0.5 <0.5
Hexachlorobenzene(HCB) 118-74-1 0.5 Ng/L -- <0.5 <0.5 <0.5 <0.5
beta-BHC 319-85-7 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
Page 71
rage 4 of 6
Work Order EB1000755
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-M.rtri-:: WATER Client sample ID GW2 SWI SW2 SW3 SW5
Client sampling date / time 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00
CAS Number LOR Unit EB1000755-001 E81000755.002 E81000755-003 ES10007SS-004 EB1000755-005
EPOEBA: Organochlodrie Posticidss (OC) -Co stlewd
gamma-BHC 58-89-9 0.5 pg/L <0.5 <0.5 <0.5 <0.5
delta-BHC 319-86-8 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Heptachlor 76-44-8 0.5 pg/L -- <0.5 <0.5 <0.5 <0.5
Aldrin 309-00-2 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
Heptachlor epoxide 1024-57-3 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
trans-Chlordane 5103-74-2 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
al p ha-Endosulfan 959-98-8 0 .5 pg/ L -- c 0.5 <0.5 <0.5 <0.5
cis-Chlordane 5103-71-9 0.5 pg/L -- <0.5 <0.5 <0.5 <0.5
Dieldrin 60-57-1 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
4.4'-DDE 72-55-9 0.5 Pg/L <0.5 <0.5 <0.5 <0.5
Endrin 72-20-8 0.5 pg/L <0.5 <0.5 <0.5 <0.5
beta-Endosulfan 33213-65-9 0.5 pg/L - <0.5 <0.5 <0.5 <0.5
4.4'-DDD 72-54-8 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
Endrin aldehyde 7421-93-4 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
Endosulfan sulfate 1031-07-8 0.5 pg/L --- <0.5 <0.5 <0.5 <0.5
4.4'-DDT 50-29-3 2 pg/L --- <2 <2 <2 <2
Endrin ketone 53494-70-5 0.5 pg/L -- <0.5 <0.5 <0.5 <0.5
Methoxychlor 72-43-5 2 Pg/L -- <2 <2 <2 <2
EPOSBB: Organophosphorus Pestlcides (OP)
Dichlorvos 62.73-7 0.5 pg/L <0.5 <0.5 <0.5
Demeton-S-methyl 919-86-8 0.5 NgIL <0.5 <0.5 <0.5 <0.5
<2 <2 <2 <2
Monocrotophos 6923-22-4 2 pg/L
Dimethoate 60-51-5 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Diazinon 333-41-5 0.5 pg/L <0.5 <0.5 <0 5 <0.5
Chlorpyrifos-methyl 5598-13-0 0.5 NgIL <0.5 <0.5 <0.5 <0.5
Parathion-methyl 298-00-0 2 pg/L <2 <2 <2 <2
Malathion 121-75-5 05 pg/L <0.5 <0.5 <0.5 <0.5
Fenthion 55-38-9 0.5 NgIL <0.5 <0.5 <0.5 <0.5
Chlorpyrifos 2921-88-2 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Parathion 56-38-2 2 Pg/L <2 <2 <2 <2
Pirimphos-ethyl 23505-41-1 0.5 Pg/L <0.5 <0.5 <0.5 <0.5
Chlorfenvinphos 470-90-6 05 pg/L <0.5 <0.5 <0.5 <0.5
Bromophos-ethyl 4824-78-6 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Fenamiphos 22224-92-6 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Prothiofos 34643-46-4 0.5 Pg/L <0.5 <0.5 <0.5 <0.5
Ethion 563-12-2 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Carbophenothion 786-19-6 0.5 pg/L <0.5 <0.5 <0.5 <0.5
Azinphos Methyl 0.5 pg/L <0.5 <0.5 <05 <05
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
_
[OCR of page images]
Page
Work Order
Chent
Pre yect
4of6
EB1000755
DUKE ENVIRONMENTAL
DE0923
Analytical Results
Sub-Vatrix: WATER
Compound
Client sample ID
Client sampling date / time
CAS Number LOR Unit
GW 2
12-JAN-2010 15:00
EB1000755-001
EPO68A: Organochliorine Pesticides (OC) - Continued
gamma-BHC 58-89-9 0.5 yo/L
delta-BHC 319-86-8 0.5 pg/L
Heptachlior 76-44-8 0.5 pg/L
Aldrin 309-00-2 0.5 pg/L
Heptachlor epoxide 1024-57-3 0.5 pg/L
trans-Chlordane 5103-74-2 05 ug/L
alpha-Endosulfan 959-98-8 0.5 pg/L
cis-Chiordane 5103-71-9 0.5 ug/L
Dieldrin 60-57-1 0.5 po/L
4,4-DDE 72-55-9 0.5 pg/L
Endrin 72-20-8 0.5 pg/L
beta-Endosulfan 33213-65-9 05 yg/L
4.4-DDD 72-54-8 0.5 pg/L
Endrin aldehyde 7421-93-4 0.5 yg/L
Endosulfan sulfate 1031-07-8 0.5 pg/L
4.4 -DDT 50-29-3 2 pg/L
Endrin ketone 53494-70-5 0.5 ug/L
Methoxychlior 72-435 2 yo/L
EPO68B: Organophosphorus Pesticides (OP)
Dichlorvos 62-73-7 0.5 pg/L
Demeton-S-methyl 919-86-8 0.5 pg/L
Monocrotophos 6923-22-4 2 pg/L
Dimethoate 60-51-5 0.5 yg/L
Diazinon 333-41-5 0.5 pg/L
Chiorpyrifos-methyl 5598-13-0 0.5 pg/L
Parathion-methy! 298-00-0 2 yg/l
Malathion 121-75-5 0.5 yo/L
Fenthion 55-38-9 0.5 pg/L
Chiorpyrifos 2921-882 05 pg/L
Parathion 56-38-2 2 pg/L
Pirimphos-ethy! 23505-41-1 0.5 ug/L
Chiorfenvinphos 470-90-6 0.5 ug/L
Bromophos-ethy! 4824-78-6 0.5 pg/L
Fenamiphos 22224-92-6 0.5 ug/L
Prothiofos 34643-46-4 0.5 pg/L
Ethion §63-12-2 0.5 pg/L
Carbophenothion 786-19-6 0.5 ug/L
Azinphos Methyl —- 0.5 pg/L
sw sw2 sw3 SW5
12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00
EB1000755-002 EB 1000755-003 EB1000755-004 EB1000755-005
Le HSH
“<05 <0.5 <0.5 <05
<0.5 <05 <0.5 <0.5
<0.5 <05 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5
<05 <05 <0.5 <0.5
<0.5 <05 <0.5 <0.5
<05 <05 <05 <0.5
<05 <0.5 <05 <05
<05 <0.5 <0.5 <05
<05 <05 <0.5 <0.5
<05 <05 <0.5 <0.5
<05 <0.5 <05 <0.5
<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5
<05 <0.5 <0.5 <0.5
<2 <2 <2 <2
<0.5 <0.5 <05 <0.5
<2 <2 <2 <2
<05 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5
<2 <2 <2 <2
<05 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <0.5 <0.5
<2 <2 <2 <2
<05 <05 <0.5 <0.5
<05 <05 <05 <0.5
<05 <0.5 <05 <05
<2 <2 <2 <2
<05 <0.5 <05 <05
<0.5 <0.5 <0.5 <05
<0.5 <0.5 <0.5 <0.5
<0.5 <0.5 <05 <0.5
<0.5 <0.5 <05 <05
<0.5 <0.5 <05 <05
<05 <05 <05 <05
<0.5 <0.5 <05 <05
‘ WIM I ihre VINNY)
Page 72
Page 506
Work Order EB1000755
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-Naha: WATER Client sample ID GW2 SW1 SW2 SW3 SW5
Client sampling date / time 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00
LOP Unit EB1000755-001 EB1000765002 E81000755-003 EB1000755-004 E61000755-005
CAS Number
EPO80/0T1: Total Petroleum Hydrocarbons
C6 - C9 Fraction 20 pg/L <20 <20 <20 <20 <20
C10 - C14 Fraction - 50 Ng/L <50 <50 <50 <50 <50
C15 - C28 Fraction -- 100 Ng/L <100 <100 <100 <100 <100
C29 - C36 Fraction 50 pg1L <50 <50 <50 <50 <50
^ C10 - C36 Fraction (sum) - 50 <50 <50 <50 <50
l ^ . -'11111 ^
Dummy Analyte ___ 1 1 1 1
EPO6BS: Organochlodna Pesticide Su
Dibromo-DDE 21655-73-2 0.1 60.2 67.7 67.9
DEF 78-48-8 0.1 74.2 74.4
EPO80S: TPH(VYBTEX Surrogates
1.2-Dichloroethane-D4 17060-07-0 0.1 % 107 102 105 106 104
Toluene-08 2037-26-5 0.1 % 104 99.7 98.9 98.6 95.6
4-Bromofluorobenzene 460-00-4 0.1 96 101 96.0 96.3 98.9 95.2
[OCR of page images]
Page : 50f6
Work Order EB1000755
Client DUKE ENVIRONMENTAL
Project DE0923 ALS
Analytical Results
Sub-Matrix: WATER Client sample ID | GW 2 . sw1 rl bh sw2 ant ; SsWw3 SW5
Client sampling date / time 12-JAN-2010 15:00 | 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00 12-JAN-2010 15:00
Compound CAS Number LOR Unit . EB1000755-001 EB1000755-002 EB1000755-003 EB1000755-004 EB1000755-005
EP080/071: Total Petroleum Hydrocarbons S. ae nny.
C6 - C9 Fraction ease 20 pg/L <20 <20 <20 ! <20 <20
C10 - C14 Fraction ael 20 yo/L ; <50 <50 <50 | <50 <50
C15 - C28 Fraction | 100 ug | <100 | <100 | <100 | <100 <100
C29 - C36 Fraction «=| 50 yt | <50 <50 <50 <50 <50
A C10 - C36 Fraction (sum) — 50 po/L <50 <50 <50 | <50 <50
MW024T: Total Algae identification i -- = ak Pea oy
Dummy Analyte ones 1 CFU/mL | os 1 1 1 1
EPO68S: Organochiorine Pesticide Surrogate ie Ro ao Bs
Dibromo-DDE 21655-73-2| 0.1 % _ 70.8 60.2 67.7 67.9
EPO68T: Organophosphorus Pesticide Surrogate
65.4 74.2 74.4
See A BE eter ee 7 Epa
1.2-Dichloroethane-D4 17060-07-0 0.1 % | 107 102 | 105 105 104
Toluene-D8 2037-265 0.1 % 104 99.7 98.9 98.6 95.6
4-Bromofiuorobenzene 460-00-4 0.1 % 101 96.0 96.3 98.9 95.2
Page 73
Page 6 of 6
Work Oster EB1000755
Client DUKE ENVIRONMENTAL
Prow I DE0923 ALS
Surrogate Control Limits
Suh-fvl:111i ,: WATER Recovery Llmlts (%)
CAS Nwntr Low High
EP0883: Organochlorine Peeddde. e e
Di bromo-D D E :1655-73-2 10
EP06BT: OrQanophosphorus Pasticidc$u p j --
78-48-8 10 110
1.2-Dlchloroethane-D4 17060-07-0 80 120
Toluene-D8 2037-26-5 88 110
4-Bromofluorobenzene 460-00-4 86 115
Page 74
ALS Laboratory Group
\^.^ i.;AL 13H; T'1 ^T;RY $ iE5T:":'3 E
Environmental Division ALS
I CERTIFICATE OF ANALYSIS
Client: DUKE ENVIRONMENTAL ALS Work Order: EBI 000755
Laboratory: ALS Environmental
Address: PO BOX 78
WURTULLA, OLD, 4575 Sydney
Date Sampled: 12.01.2010
Attention: JULIE SCHUBERT Date Received: 15.01.2010
Date Analysed: 27.01.2010
Quote: BNi423l08 Sample Type: AQUEOUS
Project: DE0923 No. of Samples: 4
ANALYSIS REPORT: PHYTOPLANKTON IDENTIFICATION & ENUMERATION
Comments:
- Under microscopic observation. EB1000755-02 was mild turbid with debris however was clear for algal analysis
but EB1000755-05 was very turbid therefore was diluted 2:10.
NOTES
Samples were preserved with Lugols Iodine solution. Duyen Nguyen
Samples were analysed in accordance with ALS Quality
Work Instruction QWI-MIC/MW024
Senior Microbiologist
(Signatory)
Results apply to sample(s) as submitted.
PTP = Potential Toxin Producers
<1 or ND = Not Detected
Organisms are reported and counted only when detected in Date Reported: 27.01.2010
the portion of 1 mL sample.
ALS Laboratory Group
TM x.c.a, wu a . f.wd n A JGTRAL W IAdos. TCRr SS W'CE S -TI L T U ABM v 41$ 1 A .`G
NATA ACYHOYp *.I.' MAfA L
l[AM- Mp./MYr
V lOOST Ey' 'C M .PS% Sc MSW'85,
t of 3
1
Page 75
I
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division ALS
ALS Sample ID: EB1000755-02 EB1000755-03 EB1000755-04 EB1000755-05
Client Sample ID: SW 1 SW 2 SW 3 SW 5
Sample Date: 12.01.2010 12.01.2010 12.01.2010 12.01.2010
Sample Time: NS 15:00 NS NS
Units: Cells/mL Cells/ml- Cells/mL Cells/mL
CYANOPHYTES (Blue-green algae)
Chroococcales
A hanoca sa spp ND ND ND 2500
Chroococcus nunitus 120 ND ND ND
Rhabdoderma s pp. ND ND 200 ND
Synechococcus spp. ND 40 2300 1800
Total Chroococcales 120 40 2500 4300
Nostocales
Anabaena spp (straight)
Total Nostocales
ND
<1
ND
<1
300
300
ND
ND
I
Oscillatoriales
Oscllatona sp p ND ND 500 ND
Pseudanabaena limnectica ND ND 300 ND
Total Oscillatoriales <1 <1 800 ND
Sti onematales
Total Sti onematales <1 <1 <1 ND
CHLOROPHYTES (Green algae)
Chlorococcales
Scenedesmus s p. ND ND ND 400
Zygnematales
Closterium sp ND ND ND 100
Cosmarium sp ND ND ND 200
Mougeotia sp. ND 30 ND ND
Total Chloro h tes <1 30 <1 700
FLAGELLATES
Eu leno h tes
Lepoclnclis s p ND ND ND 1300
Phacus s p. ND ND ND 300
Trachelomonas sp. 20 20 ND 5000
P rho h es
Pendmium sp. 20 ND ND ND
C to h es
Cryptomonas sp ND ND ND 400
Total flagellates 40 20 <1 7000
CHRYSOPHYTES (Golden algae)
Total Ch so h tes <1 <1 <1 ND
AL S Laboratory Group
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N ATA Is. w w o V:.in s 2%" .'R'1 V&.fle. Rcs4 S, M 13 IS't:: •r_a
.+*•we•.NMYtAYCj to-W" I, V W ,I Vin /A. N5 • •,.
2 of 3
Page 76
ALS Laboratory Group
ANALYTICAL CHEMISTRY & TESTING SERVICES
Environmental Division
1
ALS Sample ID: EB1000755-02 EB1000755-03 EB1000755-04 EB1000755-05
Client Sample ID: SW 1 SW 2 SW 3 SW 5
Sample Date: 12.01.2010 12.01.2010 12.01.2010 12.01.2010
Sample Time: NS 15:00 NS NS
Units: Cells/ml- Cells/ml- Cells/ml- Cells/mL
BACILLARIOPHYTES (Diatoms)
Centrics
Chaetoceros s p. ND ND 13300 ND
Cyclotella s p. ND ND 160 ND
Pennates
Fragilaria sp. ND 60 ND 100
S nedra s p. ND 20 ND 600
Achnanthes s p. 20 ND 40 ND
Cocconeis s p. 20 ND ND ND
Amphora s p. ND ND 20 ND
Entomoneis s p. ND ND 240 ND
Navicula s p. ND 30 20 150
Nitzschia sp. 20 ND 120 50
Pinnularia sp. 20 20 ND 1100
Total Bacillario h tes 80 130 13900 2000
TOTAL ALGAE 240 220 17500 14000
ND= Not Detected
NS = Not Specified
A TM ooc.nwl o ns.e.:
a L S Laboratory Group
A{SIRALIANL ORATORTV SFRVK it, PTV IID Ain W OY 986025
NATA ]Ctd0a1.L* .Of VAYAs 20, vj-ca- Rota 6-0*.N NSW 2154
N00", KUa0161M I'a^/a11a111i loJtd Bap 1J6 N I' I Pot VC NSW 1151
Plwr .51.2.87M66SSL a. .fi' 20'64Mb20
3 of 3
Page 77
CHAIN OF CUSTODY DOCUMENTATION
CL,=-,NT: Duke Environmental SAMPLER: SH
A
ADDRESS! OFFICE: PO Box 78, Wurtulla QLD 4575 MOBILE: 0418 797 956
ALS Laboratory Group
PROJECT MANAGER (PM):JUlie Schubert P-TOME. 07 5493 3322
PROJECT ID: DE0923 EMAIL REPORT TO: uGe dukenvro.com.a
SITE: Noosa Civic P.O. No.: 291825 E MA IL 'NVOIC E TO: (it different to report)
Fc^•_ L'S :E_ REv ;Dater GLOTE NO.. BN142108 ANALYSIS REQUIRED including SUITES (note - suite codes must oe listed to attract suite prices)
FOR LABOR!^TORY•USF ONLY COMMENTS /SPECIAL HANDLING ! STORAGE OR DISPOSAL 2 Notes: e.g. Highly contaminated samples
COOLER SEAL (circle appropriate) o e.g- "High PARS expelled'
O N
^ r5
m
IH(SCi Yes No u/ar ^^ 1 r^Gc- 3 i ^ a Extra volume for QC or trace LORs etc.
LE TE^TUR a o
CHILLED: Ye No F
F- U U v
SAMPLE ^N CRMATION note: S = 1 W= CONTAINER INFORMATION y N CO o
0 0 o 0 2 5
ALS IC SAMPLE IC VATRIX DATE Time -vpe /Code Total bottles 'n 3 w w 3 z
w w
GW 2 W 12101/2010 4 3 3
7 3 3
SWI w 12/01/2010 10 3 3 3
SW2 IN 12!01/2010 10 3 3 -1i Vr N( 4 /o^Gi, ,•^ (P4
"If Nif jn^
SW3 W 12/01/2010 10 3 3 3 3 3 3
SW5 w 12/01;201 10 J 3 3 3 3 3 yr r r / ( r
Environmental Division
Brisbane
Work Order
FRlnnn7c5
RELi iSH= 6Y RECEIVED BY
Name: Ste hAn Hayes Date: Name Date: 0
Of: Duke Environmental Time: i L. u) --. Of. Time: h
0
Name: Date: Name: Date: Telephone : +61.7-3243 7222
Of: Time: Of: Time:
Water Container Codes: P = Unpreservee P'astic; N = Nitric Preserved Plastic. ORC = Nitric Preserved CRC; SH = Sodium Hydroxda(Cd Preserved: S = Sodium Hydrox,ee Preserved P ast;c: AG = Amber Glass Unpreserved,
V = VCA Via, HCI Preseneo: VS = VOA Vial Sutphunc Preserved; SG = Sulfuric Preserved Amber Glass, i = HCI preserved Plastic: HS = HCI preserved Speaatron bottle: SP = Sulfuric Preserved Plastic; F = =ormaldcIrydu Preserved Glass:
Z = Zinc Acetate Preserved Bottle: E = EOTA Preserved Bottles: ST = Stele Bottle: ASS = Plastic Bag for Acid Sulphate Sods: B = Unpreserved Bag.
ALS LABORATORY GROUP COC Page ) of )
ENFM (20415)
Page 78
ALS Laboratory Group
ANALYTICAL CHEM TRY & TESTING SERVICES
Environmental Division ALS
SAMPLE RECEIPT NOTIFICATION (SRN)
Comprehensive Report
EB1000755
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia
WURTULLA QLD, AUSTRALIA 4575 4053
E-mail [email protected] E-mail [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 Page 1 of 2
Order number 291825
C-O-C number Quote number EB2009DUKENVO217 (BN/317/09)
Site Noosa Civic
Sampler SH OC Level NEPM 1999 Schedule B(3) and ALS
QCS3 requirement
Dates
Date Samples Received 15-JAN-2010 Issue Date 18-JAN-2010 16 28
Client Requested Due Date 27-JAN-2010 Scheduled Reporting Date
27-JAN-2010
Delivery Details
Mode of Delivery Carrier Temperature 12.7°C - Ice present
No of coolers/boxes 1 LARGE No of samples received 5
Sercurity Seal Intact. No. of samples analysed 5
General Comments
• This report contains the following information:
Sample Container(s)/Preservation Non-Compliances
Summary of Sample(s) and Requested Analysis
Requested Deliverables
' Samples received in appropriately pretreated and preserved containers.
• Sample(s) requiring volatile organic compound analysis received in airtight containers (ZHE).
' Breaches in recommended extraction I analysis holding times have occurred.
• The recommended holding time for Nitrite, Nitrate +/or reactive phosphorus
analysis is 48 hours from the time of sampling. As per COC the samples were
dated on 12/01/2010 and ALS received the samples on 15/01/2010.
• Please direct any turn around / technical queries to the laboratory contact designated above
• Please direct any queries related to sample condition / numbering / breakages to Maggie Kahl.
• Analytical work for this work order will be conducted at ALS Brisbane.
• Sample Disposal - Aqueous (14 days), Solid (90 days) from date of completion of work order.
Enulronmental Olulsion Brisbane
fri.. e ALS Laboratory Group
Page 79
Issue Date 18-JAN-2010 16 28
Page 2 of 2
Work c=' a -• EB1000755
Chen! DUKE ENVIRONMLNTAL ALS'
Sample Container(s)/Preservation Non-Compliances
All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.
• No sample container/ preservation non-compliance exist.
Summary of Sample(s) and Requested Analysis
Some items described below may be part of a laboratory
process
tasks.
neccessary for the execution of client requested
Packages may contain additional analyses. such as
t
the determination of moisture content and preparation L
tasks, that are included in the package.
When date(s) and/or time(s) are shown bracketed, these M o
have been assumed by the laboratory for processing
z 0 i w
purposes If the sampling time is displayed as 0:00 the
information was not provided by client. IQ m i +
Matrix: WATER
'0 fn i
o C t o c 0
0-
w I w W w 1Z Z a 2
2 U
Q: c i Q: D: y fY (Y ti IY ^ tY :6
Client sample ID 2 z CL
Laboratory sample Client sampling
ID date / time
a y ^a ° la
-
E81000755-001 12-JAN-2010_15,00 GW 2 3 3
EB1000755-002 12-JAN-2010 15:00 SW1 3 3 3 3 3 3
EB 1000755-003 12-JAN-2010 15 00 SW2 3 3 3 3
EB1000755-004 12-JAN-2010 1500 SW3 3 3 3 3
EB1000755-005 12-JAN-201015:00 SW5 3 3 3 3 3 3
N
Matrix: WATER
a
Laboratory sample Client sampling Client sample ID w 0
r ,_
ID date 'tune
EB1000755-002 12-JAN-2010 15:00 SW1 3 3
EB 1000755-003 12-JAN-2010 15:00 SW2 3 3
EB1000755-004 12-JAN-2010 1500 SW3 3 3 r
EB1000755-005 12-JAN-2010 15 00 SW5 3 3
Requested Deliverables
MS JULIE SCHUBERT
'AU Certificate of Analysis - NATA (COA) Email [email protected]
AU Interpretive OC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]
'AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected] au
A4 - AU Sample Receipt Notification - Environmental ( SRN Email [email protected] au
A4 - AU Tax Invoice (INV) Email [email protected]
Default - Chain of Custody (COC) Email [email protected]
EDI Format - ENMRG (ENMRG) Email [email protected] au
EDI Format - XTab (XTAB) Email [email protected]
I
Page 80
ALS Laboratory Group
ANALYTICAL CHEMISTRY 8 TESTING SERVICES
Environmental Division ALS
QUALITY CONTROL REPORT
EB1000755 Page 1 of8
Client DUKE ENVIRONMENTAL Laboratory Environmental Division Brisbane
Contact MS JULIE SCHUBERT Contact : Tim Kilmister
Address PO BOX 78 Address 32 Shand Street Stafford QLD Australia 4053
WURTULLA QLD, AUSTRALIA 4575
E-mail [email protected] E-mail Services. [email protected]
Telephone +61 54933322 Telephone +61-7-3243 7222
Facsimile +61 07 54933422 Facsimile +61-7-3243 7218
Project DE0923 QC Level NEPM 1999 Schedule B(3) and ALS QCS3 requirement
Site : Noosa Civic
C-O-C number -- Date Samples Received 15-JAN-2010
Sampler SH Issue Date :28-JAN-2010
Order number 291825
No of samples received 5
Quote number BN/317/09 No, of samples analysed 5
This report supersedes any previous report(s) with this reference Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for
release.
This Quality Control Report contains the following information:
• Laboratory Duplicate (DUP) Report: Relative Percentage Difference (RPD) and Acceptance Limits
• Method Blank (MB) and Laboratory Control Spike (LCS) Report: Recovery and Acceptance Limits
• Matrix Spike (MS) Report; Recovery and Acceptance Limits
NATA Accredited Laboratory 825 Signatories
This document has been electronically signed by the authorized signatories indicated below. Electronic signing has been
NATA This document is issued in
accordance with NATA
carried ou t i n comp li ance w ith proce d ures spec ifi e d i n 21 CFR P art 11 .
Signatories Position Accreditation Category
accreditation requirements.
Duyen Nguyen Senior Microbiologist Microbiology
Kim McCabe Senior Inorganic Chemist Inorganics
WnRI D Rr r m,SFD Accredited for compliance with
ACCREDITATION ISO/IEC 17025.
Sarah Ashworth Organic Chemist Organics
Enulronmcntal Diulslon Brisbane
Part 0 the ALS Laboratory Group
Page 81
Page 2of8
Work Oroler EB1000755
Client DUKE ENVIRONMENTAL
Project DE0923
General Comments
The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house
developed procedures are employed in the absence of documented standards or by client request.
Where moisture determination has been performed, results are reported on a dry weight basis.
Where a reported less than (<) result is higher than the LOR, this may he due to primary sample extractldigestate dilution and/or insuffient sample for analysis.
Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.
Key : Anonymous = Refers to samples which are not specifically part of this work order but formed part of the OC process lot
CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.
LOR = Limit of reporting
RPD = Relative Percentage Difference
# = Indicates failed OC
M
The text continues on page 82.
Used in these records
Water Quality Monitoring Report - Noosa Civic - November 2009-2010 - Eenie Creek Rd NOOSAVILLERelated documentApplication case desk ↗
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